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Properties of Matter question

2025 · 4 Apr · Shift 1 · Q57
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Properties of Matter question

2025 · 4 Apr · Shift 1 · Q57

JEE MainPhysicsProperties of MatterMCQ+4 / −1
Two liquids AAA and BBB have θA\theta_AθA​ and θB\theta_BθB​ as contact angles in a capillary tube. If K=cos⁡θA/cos⁡θBK=\cos \theta_A / \cos \theta_BK=cosθA​/cosθB​, then identify the correct statement:
  1. A
    K is negative, then liquid A and liquid B have convex meniscus.
  2. B
    KKK is negative, then liquid AAA and liquid BBB have concave meniscus.
  3. C
    K is zero, then liquid A has convex meniscus and liquid B has concave meniscus.
  4. D
    K is negative, then liquid A has concave meniscus and liquid B has convex meniscus.
View written solutionFree

Correct answer: D

  1. Relation between contact angle and meniscus

    In a capillary tube:

    • If θ<90∘\theta < 90^\circθ<90∘, then cos⁡θ>0\cos\theta > 0cosθ>0 and the liquid wets the surface, so the meniscus is concave.
    • If θ>90∘\theta > 90^\circθ>90∘, then cos⁡θ<0\cos\theta < 0cosθ<0 and the liquid does not wet the surface, so the meniscus is convex.
    • If θ=90∘\theta = 90^\circθ=90∘, then cos⁡θ=0\cos\theta = 0cosθ=0.
  2. Given quantity

    K=cos⁡θAcos⁡θBK=\frac{\cos\theta_A}{\cos\theta_B}K=cosθB​cosθA​​

    We now examine the sign of KKK.

  3. If KKK is negative

    For the ratio cos⁡θAcos⁡θB\dfrac{\cos\theta_A}{\cos\theta_B}cosθB​cosθA​​ to be negative, the numerator and denominator must have opposite signs.

    So one of cos⁡θA,cos⁡θB\cos\theta_A, \cos\theta_BcosθA​,cosθB​ is positive and the other is negative.

    That means:

    • one liquid has θ<90∘\theta<90^\circθ<90∘ ⇒\Rightarrow⇒ concave meniscus,
    • the other has θ>90∘\theta>90^\circθ>90∘ ⇒\Rightarrow⇒ convex meniscus.

    Thus, both cannot be concave and both cannot be convex.

  4. Check options

    • A: If KKK is negative, both convex meniscus. ❌ Impossible.
    • B: If KKK is negative, both concave meniscus. ❌ Impossible.
    • C: If K=0K=0K=0, then cos⁡θA=0\cos\theta_A=0cosθA​=0 (assuming denominator nonzero), so θA=90∘\theta_A=90^\circθA​=90∘. This does not imply convex meniscus for AAA. ❌
    • D: If KKK is negative, one is concave and the other is convex. This matches the sign argument. ✅
  5. About the order in option D

    Option D states: liquid AAA is concave and liquid BBB is convex.

    This corresponds to: cos⁡θA>0,cos⁡θB<0\cos\theta_A>0,\quad \cos\theta_B<0cosθA​>0,cosθB​<0 so that K=(+)(−)<0K=\frac{(+)}{(-)}<0K=(−)(+)​<0

    Hence option D is consistent.

Final Answer

D\boxed{\text{D}}D​

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