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Properties of Matter question

2019 · 12 Apr · Shift 2 · Q43
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Properties of Matter question

2019 · 12 Apr · Shift 2 · Q43

JEE MainPhysicsProperties of MatterMCQ+4 / −1
The number density of molecules of a gas depends on their distance r from the origin as, n(r)=n0e−αr4n\left( r \right) = {n_0}{e^{ - \alpha {r^4}}}n(r)=n0​e−αr4. Then the total number of molecules is proportional to :
  1. A
    n0α−3/4{n_0}{\alpha ^{ - 3/4}}n0​α−3/4
  2. B
    n0α−3{n_0}{\alpha ^{ - 3}}n0​α−3
  3. C
    n0α1/4{n_0}{\alpha ^{1/4}}n0​α1/4
  4. D
    n0α1/2\sqrt {{n_0}} {\alpha ^{1/2}}n0​​α1/2
View written solutionFree

Correct answer: A

  1. Given number density

    The number density varies with distance as n(r)=n_0 e^{-lpha r^4}.

    The total number of molecules is obtained by integrating the number density over the whole volume: N=int n(r)\,dV.

  2. Use spherical symmetry

    Since n(r)n(r)n(r) depends only on rrr, in spherical coordinates: dV=4πr2dr.dV=4\pi r^2 dr.dV=4πr2dr.

    Therefore, N=4\pi n_0 \int_0^\infty r^2 e^{-lpha r^4}dr.

  3. Extract the dependence on α\alphaα

    We only need proportionality. Let x=α1/4r⇒r=xα1/4,dr=dxα1/4.x=\alpha^{1/4}r \quad \Rightarrow \quad r=\frac{x}{\alpha^{1/4}}, \quad dr=\frac{dx}{\alpha^{1/4}}.x=α1/4r⇒r=α1/4x​,dr=α1/4dx​.

    Then, r2dr=(x2α1/2)(dxα1/4)=x2α3/4dx.r^2dr=\left(\frac{x^2}{\alpha^{1/2}}\right)\left(\frac{dx}{\alpha^{1/4}}\right)=\frac{x^2}{\alpha^{3/4}}dx.r2dr=(α1/2x2​)(α1/4dx​)=α3/4x2​dx.

    Also, e^{-lpha r^4}=e^{-x^4}.

    So the integral becomes N=4πn0∫0∞x2α3/4e−x4dx.N=4\pi n_0 \int_0^\infty \frac{x^2}{\alpha^{3/4}} e^{-x^4}dx.N=4πn0​∫0∞​α3/4x2​e−x4dx.

    Hence, N=4πn0α−3/4∫0∞x2e−x4dx.N=4\pi n_0 \alpha^{-3/4}\int_0^\infty x^2 e^{-x^4}dx.N=4πn0​α−3/4∫0∞​x2e−x4dx.

  4. Identify the proportionality

    The integral ∫0∞x2e−x4dx\int_0^\infty x^2 e^{-x^4}dx∫0∞​x2e−x4dx is just a constant, independent of n0n_0n0​ and α\alphaα.

    Therefore, N∝n0α−3/4.N \propto n_0\alpha^{-3/4}.N∝n0​α−3/4.

  5. Match with the options

    The correct option is: A: n0α−3/4\boxed{A:\ n_0\alpha^{-3/4}}A: n0​α−3/4​

  6. Comparison with stored answer

    Stored correct answer: A

    Our derived answer: A

    So they agree.

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