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Heat and Thermodynamics question

2022 · 28 Jun · Shift 2 · Q58
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  5. /2022 · 28 Jun · Shift 2 · Q58

Heat and Thermodynamics question

2022 · 28 Jun · Shift 2 · Q58

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
What will be the effect on the root mean square velocity of oxygen molecules if the temperature is doubled and oxygen molecule dissociates into atomic oxygen?
  1. A
    The velocity of atomic oxygen remains same
  2. B
    The velocity of atomic oxygen doubles
  3. C
    The velocity of atomic oxygen becomes half
  4. D
    The velocity of atomic oxygen becomes four times
View written solutionFree

Correct answer: B

  1. The root mean square speed of a गैस particle is given by

vrms=3kTmv_{\text{rms}}=\sqrt{\frac{3kT}{m}}vrms​=m3kT​​

where:

  • TTT = absolute temperature
  • mmm = mass of one particle
  • kkk = Boltzmann constant
  1. Initially, the gas consists of oxygen molecules O2\mathrm{O_2}O2​.

So,

v1=3kTmO2v_1=\sqrt{\frac{3kT}{m_{\mathrm{O_2}}}}v1​=mO2​​3kT​​

  1. Now two changes happen:
  • temperature is doubled: T→2TT \to 2TT→2T
  • oxygen molecules dissociate into atomic oxygen, so mass per particle becomes half:

mO=mO22m_{\mathrm{O}}=\frac{m_{\mathrm{O_2}}}{2}mO​=2mO2​​​

  1. Therefore the new rms speed is

v2=3k(2T)mO2/2v_2=\sqrt{\frac{3k(2T)}{m_{\mathrm{O_2}}/2}}v2​=mO2​​/23k(2T)​​

  1. Simplify:

v2=6kTmO2/2v_2=\sqrt{\frac{6kT}{m_{\mathrm{O_2}}/2}}v2​=mO2​​/26kT​​

v2=12kTmO2v_2=\sqrt{\frac{12kT}{m_{\mathrm{O_2}}}}v2​=mO2​​12kT​​

  1. Compare with the initial speed:

v1=3kTmO2v_1=\sqrt{\frac{3kT}{m_{\mathrm{O_2}}}}v1​=mO2​​3kT​​

Hence,

v2v1=12kT/mO23kT/mO2=4=2\frac{v_2}{v_1}=\sqrt{\frac{12kT/m_{\mathrm{O_2}}}{3kT/m_{\mathrm{O_2}}}}=\sqrt{4}=2v1​v2​​=3kT/mO2​​12kT/mO2​​​​=4​=2

So,

v2=2v1v_2=2v_1v2​=2v1​

  1. Option check:
  • A: same →\rightarrow→ incorrect
  • B: doubles →\rightarrow→ correct
  • C: half →\rightarrow→ incorrect
  • D: four times →\rightarrow→ incorrect

Therefore, the rms velocity becomes double.

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