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Heat and Thermodynamics question

2021 · 18 Mar · Shift 2 · Q53
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  5. /2021 · 18 Mar · Shift 2 · Q53

Heat and Thermodynamics question

2021 · 18 Mar · Shift 2 · Q53

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
Consider a sample of oxygen behaving like an ideal gas. At 300 K, the ratio of root mean square (rms) velocity to the average velocity of gas molecule would be : (Molecular weight of oxygen is 32g/mol; R = 8.3 J K −-− 1 mol −-− 1)
  1. A
    3π8\sqrt {{{3\pi } \over 8}}83π​​
  2. B
    33\sqrt {{3 \over 3}}33​​
  3. C
    83\sqrt {{8 \over 3}}38​​
  4. D
    8π3\sqrt {{{8\pi } \over 3}}38π​​
View written solutionFree

Correct answer: A

  1. Formulas for molecular speeds in an ideal gas

For an ideal gas at temperature TTT:

  • Root mean square speed: vrms=3RTMv_{\text{rms}}=\sqrt{\frac{3RT}{M}}vrms​=M3RT​​

  • Average speed: vavg=8RTπMv_{\text{avg}}=\sqrt{\frac{8RT}{\pi M}}vavg​=πM8RT​​

Here, RRR is the gas constant and MMM is molar mass.

  1. Find the required ratio

We need vrmsvavg=3RTM8RTπM\frac{v_{\text{rms}}}{v_{\text{avg}}} = \frac{\sqrt{\frac{3RT}{M}}}{\sqrt{\frac{8RT}{\pi M}}}vavg​vrms​​=πM8RT​​M3RT​​​

Using ab=ab,\frac{\sqrt{a}}{\sqrt{b}}=\sqrt{\frac{a}{b}},b​a​​=ba​​, we get vrmsvavg=3RTM8RTπM\frac{v_{\text{rms}}}{v_{\text{avg}}}=\sqrt{\frac{\frac{3RT}{M}}{\frac{8RT}{\pi M}}}vavg​vrms​​=πM8RT​M3RT​​​

Now simplify: 3RTM8RTπM=3RTM⋅πM8RT=3π8\frac{\frac{3RT}{M}}{\frac{8RT}{\pi M}}=\frac{3RT}{M}\cdot \frac{\pi M}{8RT}=\frac{3\pi}{8}πM8RT​M3RT​​=M3RT​⋅8RTπM​=83π​

Therefore, vrmsvavg=3π8\frac{v_{\text{rms}}}{v_{\text{avg}}}=\sqrt{\frac{3\pi}{8}}vavg​vrms​​=83π​​

  1. Match with options

This corresponds to: 3π8\boxed{\sqrt{\frac{3\pi}{8}}}83π​​​

So the correct option is A.

  1. Note

The ratio is independent of TTT, RRR, and MMM, so the given values are not actually needed in the final calculation.

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