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Heat and Thermodynamics question

2019 · 11 Jan · Shift 2 · Q70
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Heat and Thermodynamics question

2019 · 11 Jan · Shift 2 · Q70

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
In a process, temperature and volume of one mole of an ideal monoatomic gas are varied according to the relation VT = K, where K is a constant. In this process the temperature of the gas is increased by Δ\DeltaΔ T. The amount of heat absorbed by gas is (R is gas constant) :
  1. A
    12{1 \over 2}21​ KR Δ\DeltaΔ T
  2. B
    12{1 \over 2}21​ R Δ\DeltaΔ T
  3. C
    32{3 \over 2}23​ R Δ\DeltaΔ T
  4. D
    2K3Δ{2K \over 3}\Delta32K​Δ T
View written solutionFree

Correct answer: B

  1. Given relation

For one mole of an ideal monoatomic gas, VT=KVT=KVT=K where KKK is constant.

Also, temperature increases by ΔT\Delta TΔT.

We need the heat absorbed, δQ\delta QδQ.


  1. Use first law of thermodynamics

For an infinitesimal change, δQ=dU+δW\delta Q=dU+\delta WδQ=dU+δW

For one mole of a monoatomic ideal gas, dU=nCVdT=32R dTdU=nC_V dT=\frac{3}{2}R\,dTdU=nCV​dT=23​RdT since n=1n=1n=1 and CV=32RC_V=\frac{3}{2}RCV​=23​R.

Work done by gas: δW=P dV\delta W=P\,dVδW=PdV

So, δQ=32R dT+P dV\delta Q=\frac{3}{2}R\,dT+P\,dVδQ=23​RdT+PdV


  1. Express P dVP\,dVPdV using the given constraint

From ideal gas equation for one mole, PV=RTPV=RTPV=RT so P=RTVP=\frac{RT}{V}P=VRT​

Given, VT=K  ⟹  V=KTVT=K \implies V=\frac{K}{T}VT=K⟹V=TK​

Differentiate: dV=−KT2dTdV=-\frac{K}{T^2}dTdV=−T2K​dT

Now, P dV=RTVdVP\,dV=\frac{RT}{V}dVPdV=VRT​dV

Using V=K/TV=K/TV=K/T, P=RTK/T=RT2KP=\frac{RT}{K/T}=\frac{RT^2}{K}P=K/TRT​=KRT2​

Hence, P dV=RT2K(−KT2dT)=−R dTP\,dV=\frac{RT^2}{K}\left(-\frac{K}{T^2}dT\right)=-R\,dTPdV=KRT2​(−T2K​dT)=−RdT


  1. Find heat absorbed

Therefore, δQ=32R dT−R dT=12R dT\delta Q=\frac{3}{2}R\,dT-R\,dT=\frac{1}{2}R\,dTδQ=23​RdT−RdT=21​RdT

Integrating for temperature increase ΔT\Delta TΔT, Q=∫δQ=12R∫dT=12RΔTQ=\int \delta Q=\frac{1}{2}R\int dT=\frac{1}{2}R\Delta TQ=∫δQ=21​R∫dT=21​RΔT


  1. Match with options

Q=12RΔTQ=\frac{1}{2}R\Delta TQ=21​RΔT

So the correct option is:

B. 12RΔT\frac{1}{2}R\Delta T21​RΔT


  1. Comparison with stored answer

Stored correct answer: B

Our derived answer: B

They agree.

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