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Heat and Thermodynamics question

2019 · 12 Apr · Shift 1 · Q71
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Heat and Thermodynamics question

2019 · 12 Apr · Shift 1 · Q71

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
When M1 gram of ice at –10oC (specific heat = 0.5 cal g–1 oC–1 ) is added to M2 gram of water at 50C, finally no ice is left and the water is at 0°C. The value of latent heat of ice, in cal g–1 is :
  1. A
    50M2M1−5{{50{M_2}} \over {{M_1}}} - 5M1​50M2​​−5
  2. B
    50M2M1{{50{M_2}} \over {{M_1}}}M1​50M2​​
  3. C
    5M2M1−5{{5{M_2}} \over {{M_1}}} - 5M1​5M2​​−5
  4. D
    5M1M2−50{{5{M_1}} \over {{M_2}}} - 50M2​5M1​​−50
View written solutionFree

Correct answer: C

  1. Given data
  • Mass of ice =M1= M_1=M1​ g
  • Initial temperature of ice =−10∘C= -10^\circ C=−10∘C
  • Specific heat of ice =0.5 cal g−1 ∘C−1= 0.5\, \text{cal g}^{-1}\, ^\circ C^{-1}=0.5cal g−1∘C−1
  • Mass of water =M2= M_2=M2​ g
  • Initial temperature of water =5∘C= 5^\circ C=5∘C
  • Final temperature of mixture =0∘C= 0^\circ C=0∘C
  • No ice is left at the end

We need to find latent heat of fusion of ice, say LLL in cal g−1\text{cal g}^{-1}cal g−1.


  1. Heat required by ice

The ice first warms from −10∘C-10^\circ C−10∘C to 0∘C0^\circ C0∘C.

Heat needed for this: Q1=M1×0.5×10=5M1 calQ_1 = M_1 \times 0.5 \times 10 = 5M_1 \text{ cal}Q1​=M1​×0.5×10=5M1​ cal

Then the ice melts completely at 0∘C0^\circ C0∘C.

Heat needed for melting: Q2=M1LQ_2 = M_1 LQ2​=M1​L

So total heat absorbed by ice is Qice=5M1+M1LQ_{\text{ice}} = 5M_1 + M_1LQice​=5M1​+M1​L


  1. Heat lost by water

Water cools from 5∘C5^\circ C5∘C to 0∘C0^\circ C0∘C.

Taking specific heat of water as 1 cal g−1 ∘C−11\, \text{cal g}^{-1}\, ^\circ C^{-1}1cal g−1∘C−1, Qwater=M2×1×5=5M2 calQ_{\text{water}} = M_2 \times 1 \times 5 = 5M_2 \text{ cal}Qwater​=M2​×1×5=5M2​ cal


  1. Apply principle of calorimetry

Since final temperature is 0∘C0^\circ C0∘C and no heat is lost externally,

Heat lost by water=Heat gained by ice\text{Heat lost by water} = \text{Heat gained by ice}Heat lost by water=Heat gained by ice

So, 5M2=5M1+M1L5M_2 = 5M_1 + M_1L5M2​=5M1​+M1​L


  1. Solve for LLL

M1L=5M2−5M1M_1L = 5M_2 - 5M_1M1​L=5M2​−5M1​

L=5M2−5M1M1L = \frac{5M_2 - 5M_1}{M_1}L=M1​5M2​−5M1​​

L=5M2M1−5L = \frac{5M_2}{M_1} - 5L=M1​5M2​​−5


  1. Match with options

This matches:

Option C: 5M2M1−5\frac{5M_2}{M_1} - 5M1​5M2​​−5


  1. Comparison with stored correct answer

Stored correct answer is A: 50M2M1−5\frac{50M_2}{M_1} - 5M1​50M2​​−5

But this would be correct only if the water were initially at 50∘C50^\circ C50∘C. The question text says water is at 5∘C5^\circ C5∘C, so using the given statement, the correct expression is 5M2M1−5\frac{5M_2}{M_1} - 5M1​5M2​​−5

Hence I disagree with the stored answer. It appears there may be a typo in the question statement or in the stored answer.

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