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Heat and Thermodynamics question

2019 · 11 Jan · Shift 1 · Q68
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Heat and Thermodynamics question

2019 · 11 Jan · Shift 1 · Q68

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
A rigid diatomic ideal gas undergoes an adiabatic process at room temperature. The relation between temperature and volume for this process is TVx = constant, then x is :
  1. A
    53{5 \over 3}35​
  2. B
    25{2 \over 5}52​
  3. C
    35{3 \over 5}53​
  4. D
    23{2 \over 3}32​
View written solutionFree

Correct answer: B

  1. For an adiabatic process of an ideal gas, PVγ=constantPV^\gamma=\text{constant}PVγ=constant where γ=CPCV\gamma=\frac{C_P}{C_V}γ=CV​CP​​

  2. We want the relation between TTT and VVV.

    Using the ideal gas law, PV=nRT⇒P=nRTVPV=nRT \Rightarrow P=\frac{nRT}{V}PV=nRT⇒P=VnRT​

    Substitute into the adiabatic equation: (nRTV)Vγ=constant\left(\frac{nRT}{V}\right)V^\gamma=\text{constant}(VnRT​)Vγ=constant

    nRT Vγ−1=constantnRT\,V^{\gamma-1}=\text{constant}nRTVγ−1=constant

    Since nRnRnR is constant, TVγ−1=constantTV^{\gamma-1}=\text{constant}TVγ−1=constant

    Therefore, x=γ−1x=\gamma-1x=γ−1

  3. For a rigid diatomic ideal gas at room temperature, vibrational modes are not excited.

    So degrees of freedom: f=5f=5f=5

    Hence, CV=f2R=52RC_V=\frac{f}{2}R=\frac{5}{2}RCV​=2f​R=25​R CP=CV+R=72RC_P=C_V+R=\frac{7}{2}RCP​=CV​+R=27​R

    Therefore, γ=CPCV=72R52R=75\gamma=\frac{C_P}{C_V} = \frac{\frac{7}{2}R}{\frac{5}{2}R}=\frac{7}{5}γ=CV​CP​​=25​R27​R​=57​

  4. Now, x=γ−1=75−1=25x=\gamma-1=\frac{7}{5}-1=\frac{2}{5}x=γ−1=57​−1=52​

  5. So the correct option is: B (25)\boxed{\text{B }\left(\frac{2}{5}\right)}B (52​)​

  6. Comparison with stored answer:

    Stored correct answer = B

    Our derived answer = B

    Hence, they agree.

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