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Atoms and Nuclei question

2023 · 12 Apr · Shift 1 · Q58
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Atoms and Nuclei question

2023 · 12 Apr · Shift 1 · Q58

JEE MainPhysicsAtoms and NucleiMCQ+4 / −1
A 12.5 eV12.5 \mathrm{~eV}12.5 eV electron beam is used to bombard gaseous hydrogen at room temperature. The number of spectral lines emitted will be:
  1. A
    2
  2. B
    4
  3. C
    3
  4. D
    1
View written solutionFree

Correct answer: C

  1. Find which excited states of hydrogen can be reached

For hydrogen, the energy of the nnnth level is En=−13.6n2 eVE_n=-\frac{13.6}{n^2}\ \text{eV}En​=−n213.6​ eV

If the atom starts in the ground state (n=1)(n=1)(n=1), then the excitation energy to level nnn is ΔE=En−E1=13.6(1−1n2) eV\Delta E = E_n-E_1 = 13.6\left(1-\frac{1}{n^2}\right) \text{ eV}ΔE=En​−E1​=13.6(1−n21​) eV

The incident electrons have energy 12.5 eV12.5\ \text{eV}12.5 eV. So only those excitations are possible for which 13.6(1−1n2)≤12.513.6\left(1-\frac{1}{n^2}\right) \le 12.513.6(1−n21​)≤12.5

Now check successive levels:

  • For n=2n=2n=2: ΔE=13.6(1−14)=13.6⋅34=10.2 eV\Delta E = 13.6\left(1-\frac14\right)=13.6\cdot \frac34=10.2\ \text{eV}ΔE=13.6(1−41​)=13.6⋅43​=10.2 eV Possible.

  • For n=3n=3n=3: ΔE=13.6(1−19)=13.6⋅89≈12.09 eV\Delta E = 13.6\left(1-\frac19\right)=13.6\cdot \frac89\approx 12.09\ \text{eV}ΔE=13.6(1−91​)=13.6⋅98​≈12.09 eV Possible.

  • For n=4n=4n=4: ΔE=13.6(1−116)=13.6⋅1516=12.75 eV\Delta E = 13.6\left(1-\frac1{16}\right)=13.6\cdot \frac{15}{16}=12.75\ \text{eV}ΔE=13.6(1−161​)=13.6⋅1615​=12.75 eV Not possible, since 12.75>12.512.75>12.512.75>12.5.

So the highest excited state accessible is n=3n=3n=3.


  1. List all possible emitted spectral lines

Once atoms are excited up to n=3n=3n=3, de-excitation can produce all possible downward transitions among levels 3,2,13,2,13,2,1:

  • 3→23 \to 23→2
  • 3→13 \to 13→1
  • 2→12 \to 12→1

Thus total number of distinct spectral lines is n(n−1)2=3⋅22=3\frac{n(n-1)}{2}=\frac{3\cdot 2}{2}=32n(n−1)​=23⋅2​=3


  1. Match with options

The number of spectral lines emitted is 3\boxed{3}3​

So the correct option is C.

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