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Thermodynamics question

2023 · 10 Apr · Shift 1 · Q9
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  5. /2023 · 10 Apr · Shift 1 · Q9

Thermodynamics question

2023 · 10 Apr · Shift 1 · Q9

JEE MainChemistryThermodynamicsMCQ+4 / −1

Given

(A) 2CO(g)+O2(g)→2CO2(g)\mathrm{2CO(g)+O_2(g)\to 2CO_2(g)}2CO(g)+O2​(g)→2CO2​(g) ΔH10=−x kJ mol−1\mathrm{\Delta H_1^0=-x~kJ~mol^{-1}}ΔH10​=−x kJ mol−1
(B) C(graphite)+O2(g)→CO2(g)\mathrm{C(graphite)+O_2(g)\to CO_2(g)}C(graphite)+O2​(g)→CO2​(g) ΔH20=−y kJ mol−1\mathrm{\Delta H_2^0=-y~kJ~mol^{-1}}ΔH20​=−y kJ mol−1

ΔH0\mathrm{\Delta H^0}ΔH0 for the reaction

C(graphite)+12O2(g)→CO(g)\mathrm{C(graphite)+\frac{1}{2}O_2(g)\to CO(g)}C(graphite)+21​O2​(g)→CO(g) is :

  1. A
    x−2y2\frac{x-2y}{2}2x−2y​
  2. B
    x+2y2\frac{x+2y}{2}2x+2y​
  3. C
    2y−x2y-x2y−x
  4. D
    2x−y2\frac{2x-y}{2}22x−y​
View written solutionFree

Correct answer: A

  1. Write the given reactions

(A)2 CO(g)+O2(g)→2 CO2(g),ΔH1∘=−x\text{(A)}\quad 2\,CO(g)+O_2(g) \to 2\,CO_2(g), \qquad \Delta H_1^\circ=-x(A)2CO(g)+O2​(g)→2CO2​(g),ΔH1∘​=−x

(B)C(graphite)+O2(g)→CO2(g),ΔH2∘=−y\text{(B)}\quad C(\text{graphite})+O_2(g) \to CO_2(g), \qquad \Delta H_2^\circ=-y(B)C(graphite)+O2​(g)→CO2​(g),ΔH2∘​=−y

We need to find ΔH∘\Delta H^\circΔH∘ for:

C(graphite)+12O2(g)→CO(g)C(\text{graphite})+\frac{1}{2}O_2(g) \to CO(g)C(graphite)+21​O2​(g)→CO(g)


  1. First simplify reaction (A)

Divide reaction (A) by 2:

CO(g)+12O2(g)→CO2(g)CO(g)+\frac{1}{2}O_2(g) \to CO_2(g)CO(g)+21​O2​(g)→CO2​(g)

So its enthalpy becomes:

ΔH∘=−x2\Delta H^\circ = -\frac{x}{2}ΔH∘=−2x​


  1. Use Hess's law

We know:

C(graphite)+O2(g)→CO2(g)ΔH∘=−yC(\text{graphite})+O_2(g) \to CO_2(g) \qquad \Delta H^\circ=-yC(graphite)+O2​(g)→CO2​(g)ΔH∘=−y

Also:

CO(g)+12O2(g)→CO2(g)ΔH∘=−x2CO(g)+\frac{1}{2}O_2(g) \to CO_2(g) \qquad \Delta H^\circ=-\frac{x}{2}CO(g)+21​O2​(g)→CO2​(g)ΔH∘=−2x​

Reverse the second equation:

CO2(g)→CO(g)+12O2(g)CO_2(g) \to CO(g)+\frac{1}{2}O_2(g)CO2​(g)→CO(g)+21​O2​(g)

Then:

ΔH∘=+x2\Delta H^\circ=+\frac{x}{2}ΔH∘=+2x​

Now add it to reaction (B):

C(graphite)+O2(g)→CO2(g)(−y)C(\text{graphite})+O_2(g) \to CO_2(g) \qquad (-y)C(graphite)+O2​(g)→CO2​(g)(−y)

CO2(g)→CO(g)+12O2(g)(+x2)CO_2(g) \to CO(g)+\frac{1}{2}O_2(g) \qquad \left(+\frac{x}{2}\right)CO2​(g)→CO(g)+21​O2​(g)(+2x​)

Adding,

C(graphite)+O2(g)→CO(g)+12O2(g)C(\text{graphite})+O_2(g) \to CO(g)+\frac{1}{2}O_2(g)C(graphite)+O2​(g)→CO(g)+21​O2​(g)

Cancel 12O2\frac{1}{2}O_221​O2​ from both sides:

C(graphite)+12O2(g)→CO(g)C(\text{graphite})+\frac{1}{2}O_2(g) \to CO(g)C(graphite)+21​O2​(g)→CO(g)

Hence,

ΔH∘=−y+x2\Delta H^\circ=-y+\frac{x}{2}ΔH∘=−y+2x​

ΔH∘=x−2y2\Delta H^\circ=\frac{x-2y}{2}ΔH∘=2x−2y​


  1. Match with the options

ΔH∘=x−2y2\boxed{\Delta H^\circ=\frac{x-2y}{2}}ΔH∘=2x−2y​​

So the correct option is:

A\boxed{\text{A}}A​

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