JEE MainChemistryThermodynamicsMCQ+4 / −1
On the basis of the following thermochemical data : (= 0) (l) (aq) + (aq); = 57.32 kJ (g) + (l); = -286.20 kJ The value of enthalpy of formation of ion at 25oC is :
- A-22.88 kJ
- B-228.88 kJ
- C+228.88 kJ
- D-343.52 kJ
View written solutionFree
Correct answer: B
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Given thermochemical equations
We are given:
and
Also,
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Target reaction
We need the enthalpy of formation of , i.e. for the reaction:
Strictly in aqueous convention, this can be viewed through Hess's law using .
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Apply Hess's law
Add the two given equations:
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Formation of water:
-
Ionization of water:
On adding, cancels:
Therefore,
-
-
Use standard enthalpy of formation relation
For the above reaction,
since reactants are elements in standard state.
Given:
Hence,
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Option check
- A: kJ ❌
- B: kJ ✅
- C: kJ ❌
- D: kJ ❌
Final answer: Option B.
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