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Thermodynamics question

2008 · Shift 0 · Q10
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Thermodynamics question

2008 · Shift 0 · Q10

JEE MainChemistryThermodynamicsMCQ+4 / −1
Oxidising power of chlorine in aqueous solution can be determined by the parameters indicated below: 12Cl2(g){1 \over 2}C{l_2}(g)21​Cl2​(g) →12ΔdissHΘ\xrightarrow{{1 \over 2}{\Delta _{diss}}{H^\Theta }}21​Δdiss​HΘ​ Cl(g)→ΔegHΘCl−(g)→ΔHydHΘCl−(aq)Cl(g)\xrightarrow{{\Delta _{eg}}{H^\Theta }} C{l^ - }(g)\xrightarrow{{\Delta _{Hyd}}{H^\Theta }} C{l^ - }(aq)Cl(g)Δeg​HΘ​Cl−(g)ΔHyd​HΘ​Cl−(aq)(Using the data, ΔdissHCl2Θ{\Delta _{diss}}H_{C{l_2}}^\ThetaΔdiss​HCl2​Θ​= 240 kJ/mol, ΔegHClΘ{\Delta _{eg}}H_{Cl}^\ThetaΔeg​HClΘ​= -349 kJ/mol, ΔhydHCl−Θ{\Delta _{hyd}}H_{C{l^ - }}^\ThetaΔhyd​HCl−Θ​ = - 381 kJ/mol) will be :
  1. A
    +152 kJ mol−1
  2. B
    −610 kJ mol−1
  3. C
    −850 kJ mol−1
  4. D
    +120 kJ mol−1
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