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Thermodynamics question

2006 · Shift 0 · Q2
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Thermodynamics question

2006 · Shift 0 · Q2

JEE MainChemistryThermodynamicsMCQ+4 / −1
An ideal gas is allowed to expand both reversibly and irreversibly in an isolated system. If Ti is the initial temperature and Tf is the final temperature, which of the following statements is correct?
  1. A
    (Tf)irrev > (Tf)rev
  2. B
    (Tf)rev = (Tf)irrev
  3. C
    Tf > Ti for reversible process but Tf = Ti for irreversible process
  4. D
    Tf = Ti for both reversible and irreversible processes
View written solutionFree

Correct answer: D

  1. Key idea: isolated system

    For an isolated system, q=0,w=0q=0, \qquad w=0q=0,w=0 so from the first law, ΔU=q+w=0.\Delta U = q+w = 0.ΔU=q+w=0.

  2. For an ideal gas

    The internal energy of an ideal gas depends only on temperature: U=U(T).U = U(T).U=U(T). Hence, ΔU=nCV(Tf−Ti).\Delta U = nC_V (T_f-T_i).ΔU=nCV​(Tf​−Ti​).

    Since ΔU=0\Delta U=0ΔU=0, we get nCV(Tf−Ti)=0⇒Tf=Ti.nC_V (T_f-T_i)=0 \Rightarrow T_f=T_i.nCV​(Tf​−Ti​)=0⇒Tf​=Ti​.

  3. Effect of reversible vs irreversible expansion

    Whether the expansion is reversible or irreversible does affect the path, but for an ideal gas in an isolated system, the total change in internal energy remains zero in both cases.

    Therefore, in both processes, Tf=Ti.T_f = T_i.Tf​=Ti​.

  4. Check options

    • A: (Tf)irrev>(Tf)rev(T_f)_{\text{irrev}} > (T_f)_{\text{rev}}(Tf​)irrev​>(Tf​)rev​ ❌
    • B: (Tf)rev=(Tf)irrev(T_f)_{\text{rev}} = (T_f)_{\text{irrev}}(Tf​)rev​=(Tf​)irrev​ ✅
    • C: Tf>TiT_f>T_iTf​>Ti​ for reversible but Tf=TiT_f=T_iTf​=Ti​ for irreversible ❌
    • D: Tf=TiT_f=T_iTf​=Ti​ for both reversible and irreversible ✅
  5. Subtlety about options B and D

    Since both final temperatures equal the same initial temperature, both statements BBB and DDD are true mathematically: (Tf)rev=(Tf)irrev=Ti.(T_f)_{\text{rev}}=(T_f)_{\text{irrev}}=T_i.(Tf​)rev​=(Tf​)irrev​=Ti​.

    If forced to choose the most complete option, D is the best statement because it explicitly gives the actual relation with TiT_iTi​.


Conclusion: Tf=Ti for both reversible and irreversible expansion of an ideal gas in an isolated system.T_f=T_i \text{ for both reversible and irreversible expansion of an ideal gas in an isolated system.}Tf​=Ti​ for both reversible and irreversible expansion of an ideal gas in an isolated system. So the correct choice should be D (and note that B is also implied true).

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