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Structure of Atom question

2024 · 30 Jan · Shift 2 · Q23
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Structure of Atom question

2024 · 30 Jan · Shift 2 · Q23

JEE MainChemistryStructure of AtomNumerical+4 / −1
Number of spectral lines obtained in He+\mathrm{He}^{+}He+ spectra, when an electron makes transition from fifth excited state to first excited state will be
Numerical answer
View written solutionFree

Correct answer: 10

  1. Identify the energy levels involved

For a hydrogen-like species such as He+\mathrm{He}^+He+, the spectral lines depend only on the initial and final principal quantum numbers.

  • Fifth excited state means: n=6n = 6n=6 because ground state is n=1n=1n=1, first excited is n=2n=2n=2, ..., fifth excited is n=6n=6n=6.

  • First excited state means: n=2n = 2n=2

So the electron can undergo transitions among the levels: n=6,5,4,3,2n = 6, 5, 4, 3, 2n=6,5,4,3,2

  1. Count all possible downward transitions

Each distinct pair of levels gives one spectral line.

If there are mmm energy levels involved, the total number of possible emission lines is: N=m(m−1)2N = \frac{m(m-1)}{2}N=2m(m−1)​

Here the involved levels are 6,5,4,3,26,5,4,3,26,5,4,3,2, so m=5m = 5m=5

Thus, N=5⋅42=10N = \frac{5\cdot 4}{2} = 10N=25⋅4​=10

  1. Alternative listing of transitions

Possible transitions are:

  • 6→56 \to 56→5
  • 6→46 \to 46→4
  • 6→36 \to 36→3
  • 6→26 \to 26→2
  • 5→45 \to 45→4
  • 5→35 \to 35→3
  • 5→25 \to 25→2
  • 4→34 \to 34→3
  • 4→24 \to 24→2
  • 3→23 \to 23→2

Total =10= 10=10 lines.

  1. Final answer

The number of spectral lines obtained is: 10\boxed{10}10​

  1. Comparison with stored answer

Stored correct answer = 101010.

This matches the derived answer.

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