JEE MainChemistryStructure of AtomNumerical+4 / −1
The longest wavelength of light that can be used for the ionisation of lithium atom (Li) in its ground state is x 10 8 m. The value of x is . (Nearest Integer). (Given : Energy of the electron in the first shell of the hydrogen atom is 2.2 10 18 J ; h = 6.63 10 34 Js and c = 3 108 ms 1)
Numerical answer
View written solutionFree
Correct answer: 4
- Ionisation energy of hydrogen in ground state
Given energy of electron in first shell of H atom:
So, ionisation energy of H from ground state is:
- Ionisation energy of lithium atom
Lithium has configuration . The electron removed during first ionisation is the outermost electron.
Using Bohr-like approximation for hydrogen-like outer electron:
For Li, outer electron is in second shell, so take and :
Hence ionisation energy required is:
- Longest wavelength for ionisation
For threshold ionisation,
So,
Substitute values:
Thus, so
Nearest integer:
- Comparison with stored answer
Stored correct answer = .
Our derived answer also = .
More from Structure of Atom
- The pair, in which ions are isoelectronic with is :2022 · MCQ
- The minimum energy that must be possessed by photons in order to produce the photoelectric effect with platinum metal is : [Given : The threshold frequency of platinum is 1.3 1015 s 1 and h = 6.6 10 34 J s.]2022 · MCQ
- The wavelength of an electron and a neutron will become equal when the velocity of the electron is times the velocity of neutron. The value of is . (Nearest Integer) (Mass of electron is …2022 · Numerical
- Consider an imaginary ion . The nucleus contains ''% more neutrons than the number of electrons in the ion. The value of 'a' is . [nearest integer]2022 · Numerical
- If the radius of the 3rd Bohr's orbit of hydrogen atom is r3 and the radius of 4th Bohr's orbit is r4. Then :2022 · MCQ
- The number of radial and angular nodes in 4d orbital are, respectively2022 · MCQ
- Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R. Assertion A: Energy of orbital of hydrogen atom is greater than that of orbital of lithium. Reason R:…2022 · MCQ
- The correct decreasing order of energy for the orbitals having, following set of quantum numbers : (A) n = 3, l = 0, m = 0 (B) n = 4, l = 0, m = 0 (C) n = 3, l = 1, m = 0 (D) n = 3, l = 2, m = 1 is :2022 · MCQ