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Structure of Atom question

2021 · 16 Mar · Shift 2 · Q18
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Structure of Atom question

2021 · 16 Mar · Shift 2 · Q18

JEE MainChemistryStructure of AtomNumerical+4 / −1
The number of orbitals with n = 5, m1 = +2 is ‾\underline{\hspace{2cm}}​. (Round off to the Nearest Integer).
Numerical answer
View written solutionFree

Correct answer: 3

  1. We are given:

    • Principal quantum number: n=5n = 5n=5
    • Magnetic quantum number: ml=+2m_l = +2ml​=+2
  2. For a given principal quantum number nnn, the azimuthal quantum number lll can take values: l=0,1,2,3,…,n−1l = 0, 1, 2, 3, \dots, n-1l=0,1,2,3,…,n−1 So for n=5n=5n=5: l=0,1,2,3,4l = 0,1,2,3,4l=0,1,2,3,4

  3. For a given lll, the magnetic quantum number mlm_lml​ can take values: ml=−l,−(l−1),…,0,…,+(l−1),+lm_l = -l, -(l-1), \dots, 0, \dots, +(l-1), +lml​=−l,−(l−1),…,0,…,+(l−1),+l

  4. We need those orbitals for which ml=+2m_l = +2ml​=+2 is possible. This requires: l≥2l \ge 2l≥2 because only then +2+2+2 lies in the allowed range from −l-l−l to +l+l+l.

  5. Among the allowed lll values for n=5n=5n=5:

    • l=0l=0l=0 : ml=+2m_l=+2ml​=+2 not possible
    • l=1l=1l=1 : ml=+2m_l=+2ml​=+2 not possible
    • l=2l=2l=2 : ml=+2m_l=+2ml​=+2 possible
    • l=3l=3l=3 : ml=+2m_l=+2ml​=+2 possible
    • l=4l=4l=4 : ml=+2m_l=+2ml​=+2 possible
  6. Thus, the possible orbitals correspond to: l=2,3,4l = 2,3,4l=2,3,4 That gives a total of: 333 orbitals.

  7. Therefore, the required number of orbitals is: 3\boxed{3}3​

  8. Comparison with stored correct answer:

    • Derived answer = 333
    • Stored correct answer = 333
    • They match.
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