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Structure of Atom question

2019 · 11 Jan · Shift 2 · Q18
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Structure of Atom question

2019 · 11 Jan · Shift 2 · Q18

JEE MainChemistryStructure of AtomMCQ+4 / −1
The de Broglie wavelength (λ\lambdaλ) associated with a photoelectron varies with the frequency (v) of the incident radiation as, [v0 is threshold frequency] :
  1. A
    λ ∞ 1(v−v0)32\lambda \,\infty \,{1 \over {{{\left( {v - {v_0}} \right)}^{{3 \over 2}}}}}λ∞(v−v0​)23​1​
  2. B
    λ ∞ 1(v−v0)14\lambda \,\infty \,{1 \over {{{\left( {v - {v_0}} \right)}^{{1 \over 4}}}}}λ∞(v−v0​)41​1​
  3. C
    λ ∞ 1(v−v0)\lambda \,\infty \,{1 \over {\left( {v - {v_0}} \right)}}λ∞(v−v0​)1​
  4. D
    λ ∞ 1(v−v0)12\lambda \,\infty \,{1 \over {{{\left( {v - {v_0}} \right)}^{{1 \over 2}}}}}λ∞(v−v0​)21​1​
View written solutionFree

Correct answer: D

  1. Use Einstein’s photoelectric equation

For a photoelectron emitted by radiation of frequency ν\nuν:

hν=hν0+Kmax⁡h\nu = h\nu_0 + K_{\max}hν=hν0​+Kmax​

So,

Kmax⁡=h(ν−ν0)K_{\max} = h(\nu-\nu_0)Kmax​=h(ν−ν0​)

where ν0\nu_0ν0​ is the threshold frequency.

  1. Relate kinetic energy to momentum

For the emitted electron,

K=p22mK = \frac{p^2}{2m}K=2mp2​

Hence,

p=2mKp = \sqrt{2mK}p=2mK​

Substituting K=h(ν−ν0)K = h(\nu-\nu_0)K=h(ν−ν0​):

p=2mh(ν−ν0)p = \sqrt{2m h(\nu-\nu_0)}p=2mh(ν−ν0​)​

  1. Use de Broglie relation

The de Broglie wavelength is

λ=hp\lambda = \frac{h}{p}λ=ph​

Therefore,

λ=h2mh(ν−ν0)\lambda = \frac{h}{\sqrt{2m h(\nu-\nu_0)}}λ=2mh(ν−ν0​)​h​

Thus,

λ∝1ν−ν0\lambda \propto \frac{1}{\sqrt{\nu-\nu_0}}λ∝ν−ν0​​1​

  1. Match with the options

This corresponds to:

λ∝1(ν−ν0)1/2\lambda \propto \frac{1}{(\nu-\nu_0)^{1/2}}λ∝(ν−ν0​)1/21​

So the correct option is D.

  1. Check all options briefly
  • A: λ∝1(ν−ν0)3/2\lambda \propto \dfrac{1}{(\nu-\nu_0)^{3/2}}λ∝(ν−ν0​)3/21​ ❌
  • B: λ∝1(ν−ν0)1/4\lambda \propto \dfrac{1}{(\nu-\nu_0)^{1/4}}λ∝(ν−ν0​)1/41​ ❌
  • C: λ∝1(ν−ν0)\lambda \propto \dfrac{1}{(\nu-\nu_0)}λ∝(ν−ν0​)1​ ❌
  • D: λ∝1(ν−ν0)1/2\lambda \propto \dfrac{1}{(\nu-\nu_0)^{1/2}}λ∝(ν−ν0​)1/21​ ✅

Hence, the derived answer matches the stored correct answer.

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