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Structure of Atom question

2018 · 15 Apr · Shift 2 · Q21
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Structure of Atom question

2018 · 15 Apr · Shift 2 · Q21

JEE MainChemistryStructure of AtomMCQ+4 / −1
The de-Broglie's wavelength of electron present in first Bohr orbit of 'H' atom is :
  1. A
    0.529 A∘\mathop {\rm A}\limits^ \circA∘
  2. B
    2 π×\pi \timesπ× 0.529 A∘\mathop {\rm A}\limits^ \circA∘
  3. C
    0.5292πA∘{{0.529} \over {2\pi }}\mathop {\rm A}\limits^ \circ2π0.529​A∘
  4. D
    4 ×\times× 0.529 A∘\mathop {\rm A}\limits^ \circA∘
View written solutionFree

Correct answer: B

  1. Use Bohr’s quantization condition

    For an electron in the Bohr orbit, 2πrn=nλ2\pi r_n = n\lambda2πrn​=nλ where rnr_nrn​ is the radius of the nnnth orbit and λ\lambdaλ is the de-Broglie wavelength.

  2. For the first Bohr orbit

    In hydrogen atom, for the first orbit: n=1,r1=0.529 A˚n=1, \quad r_1 = 0.529\,\text{Å}n=1,r1​=0.529A˚

    So, 2πr1=λ2\pi r_1 = \lambda2πr1​=λ

  3. Substitute the value of r1r_1r1​

    λ=2π×0.529 A˚\lambda = 2\pi \times 0.529\,\text{Å}λ=2π×0.529A˚

  4. Match with the options

    This corresponds to: Option B: 2π×0.529 A˚2\pi \times 0.529\,\text{Å}2π×0.529A˚

  5. Check other options briefly

    • A: 0.529 A˚0.529\,\text{Å}0.529A˚ is just the radius, not the wavelength.
    • C: 0.5292π A˚\dfrac{0.529}{2\pi}\,\text{Å}2π0.529​A˚ is incorrect.
    • D: 4×0.529 A˚4\times 0.529\,\text{Å}4×0.529A˚ is also incorrect.

Therefore, the correct answer is B.

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