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Structure of Atom question

2018 · 15 Apr · Shift 1 · Q21
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Structure of Atom question

2018 · 15 Apr · Shift 1 · Q21

JEE MainChemistryStructure of AtomMCQ+4 / −1
Ejection of the photoelectron from metal in the photoelectric experiment can be stopped by applying 0.5 V when the radiation of 250 nm is used. The work function of the metal is :
  1. A
    4 eV
  2. B
    4.5 eV
  3. C
    5 eV
  4. D
    5.5 eV
View written solutionFree

Correct answer: B

  1. Use Einstein’s photoelectric equation

    hν=ϕ+Kmax⁡h\nu = \phi + K_{\max}hν=ϕ+Kmax​

    Here,

    • ϕ\phiϕ = work function of the metal
    • Kmax⁡K_{\max}Kmax​ = maximum kinetic energy of emitted electron
  2. Relate stopping potential to kinetic energy

    The stopping potential is V0=0.5 VV_0 = 0.5\,\text{V}V0​=0.5V, so

    Kmax⁡=eV0=0.5 eVK_{\max} = eV_0 = 0.5\,\text{eV}Kmax​=eV0​=0.5eV

  3. Calculate energy of incident radiation

    Wavelength given:

    λ=250 nm\lambda = 250\,\text{nm}λ=250nm

    Photon energy:

    E=hcλE = \frac{hc}{\lambda}E=λhc​

    Using the standard relation

    E(eV)=1240λ(nm)E(\text{eV}) = \frac{1240}{\lambda(\text{nm})}E(eV)=λ(nm)1240​

    E=1240250=4.96 eVE = \frac{1240}{250} = 4.96\,\text{eV}E=2501240​=4.96eV

  4. Find the work function

    ϕ=E−Kmax⁡\phi = E - K_{\max}ϕ=E−Kmax​

    ϕ=4.96−0.5=4.46 eV\phi = 4.96 - 0.5 = 4.46\,\text{eV}ϕ=4.96−0.5=4.46eV

    This is approximately

    ϕ≈4.5 eV\phi \approx 4.5\,\text{eV}ϕ≈4.5eV

  5. Match with the options

    The correct option is:

    B: 4.5 eV4.5\,\text{eV}4.5eV

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