JEE MainChemistryStructure of AtomMCQ+4 / −1
The graph between and r (radial distance) is shown below. This represents : 

- A3s orbital
- B2s orbital
- C2p orbital
- D1s orbital
View written solutionFree
Correct answer: B
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We are asked to identify an orbital from the graph of versus radial distance .
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Key idea:
- The number of radial nodes helps identify the orbital.
- For a hydrogen-like orbital: where:
- = principal quantum number
- = azimuthal quantum number
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Now check each option:
A: orbital
- For , ,
- Radial nodes:
- So its vs graph should show two radial nodes.
B: orbital
- For , ,
- Radial nodes:
- So its graph should show one radial node.
C: orbital
- For , ,
- Radial nodes:
- So it has no radial node.
- Also, for a orbital, at .
D: orbital
- For , ,
- Radial nodes:
- So it has no radial node.
- Also, is maximum at and then decreases smoothly.
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From the given graph, the wave function probability density shows one radial node (it becomes zero once and then rises again).
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Therefore, the orbital represented is:
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Option-wise conclusion:
- A: Incorrect
- B: Correct
- C: Incorrect
- D: Incorrect
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Comparison with stored correct answer:
- Stored correct answer = B
- Derived answer = B
- Hence, they agree.
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