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Some Basic Concepts of Chemistry question

2023 · 25 Jan · Shift 1 · Q18
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Some Basic Concepts of Chemistry question

2023 · 25 Jan · Shift 1 · Q18

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
In sulphur estimation, 0.471 g of an organic compound gave 1.4439 g of barium sulphate. The percentage of sulphur in the compound is ‾\underline{\hspace{2cm}}​ (Nearest Integer) (Given : Atomic mass Ba: 137 u, S: 32 u, O: 16 u)
Numerical answer
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Correct answer: 42

  1. Find molar mass of BaSO4\mathrm{BaSO_4}BaSO4​

M(BaSO4)=137+32+4×16=137+32+64=233M(\mathrm{BaSO_4}) = 137 + 32 + 4\times 16 = 137 + 32 + 64 = 233M(BaSO4​)=137+32+4×16=137+32+64=233

  1. Mass of sulphur present in 1.4439 1.4439\,1.4439g of BaSO4\mathrm{BaSO_4}BaSO4​

In 233 233\,233g of BaSO4\mathrm{BaSO_4}BaSO4​, mass of sulphur =32 = 32\,=32g.

So, in 1.4439 1.4439\,1.4439g of BaSO4\mathrm{BaSO_4}BaSO4​, mass of sulphur is

mS=1.4439×32233m_S = 1.4439\times \frac{32}{233}mS​=1.4439×23332​

mS=0.1984 gm_S = 0.1984\,\text{g}mS​=0.1984g

  1. Percentage of sulphur in the organic compound

Mass of organic compound =0.471 = 0.471\,=0.471g.

%S=0.19840.471×100\%S = \frac{0.1984}{0.471}\times 100%S=0.4710.1984​×100

%S≈42.12%\%S \approx 42.12\%%S≈42.12%

  1. Nearest integer

42\boxed{42}42​

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