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Some Basic Concepts of Chemistry question

2021 · 31 Aug · Shift 2 · Q19
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Some Basic Concepts of Chemistry question

2021 · 31 Aug · Shift 2 · Q19

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
Sodium oxide reacts with water to produce sodium hydroxide. 20.0 g of sodium oxide is dissolved in 500 mL of water. Neglecting the change in volume, the concentration of the resulting NaOH solution is ‾×\underline{\hspace{2cm}}\times​× 10 −-− 1 M. (Nearest integer) [Atomic mass : Na = 23.0, O = 16.0, H = 1.0]
Numerical answer
View written solutionFree

Correct answer: 13

  1. Write the reaction

    Sodium oxide reacts with water as: Na2O+H2O→2NaOH\mathrm{Na_2O + H_2O \rightarrow 2NaOH}Na2​O+H2​O→2NaOH

  2. Calculate molar mass of Na2O\mathrm{Na_2O}Na2​O

    M(Na2O)=2(23)+16=62 g mol−1M(\mathrm{Na_2O}) = 2(23) + 16 = 62\,\text{g mol}^{-1}M(Na2​O)=2(23)+16=62g mol−1

  3. Calculate moles of Na2O\mathrm{Na_2O}Na2​O used

    Given mass = 20.0 20.0\,20.0g

    n(Na2O)=20.062=0.3226 moln(\mathrm{Na_2O}) = \frac{20.0}{62} = 0.3226\,\text{mol}n(Na2​O)=6220.0​=0.3226mol

  4. Use stoichiometry to find moles of NaOH\mathrm{NaOH}NaOH formed

    From the balanced equation: 1 mol Na2O→2 mol NaOH1\,\text{mol } \mathrm{Na_2O} \rightarrow 2\,\text{mol } \mathrm{NaOH}1mol Na2​O→2mol NaOH

    Therefore, n(NaOH)=2×0.3226=0.6452 moln(\mathrm{NaOH}) = 2 \times 0.3226 = 0.6452\,\text{mol}n(NaOH)=2×0.3226=0.6452mol

  5. Calculate molarity of resulting solution

    Volume of solution = 500 500\,500mL = 0.500 0.500\,0.500L

    M=0.64520.500=1.2904 MM = \frac{0.6452}{0.500} = 1.2904\,\text{M}M=0.5000.6452​=1.2904M

  6. Match with the given format

    We need: concentration=‾×10−1 M\text{concentration} = \underline{\hspace{1cm}} \times 10^{-1}\,\text{M}concentration=​×10−1M

    Since 1.2904 M=12.904×10−1 M1.2904\,\text{M} = 12.904 \times 10^{-1}\,\text{M}1.2904M=12.904×10−1M

    Nearest integer =13= 13=13.

  7. Comparison with stored answer

    Derived answer = 131313

    Stored correct answer = 131313

    Hence, the answers agree.

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