View written solutionFree
Correct answer: 5
- Let the saturated acyclic compound be a hydroxy compound
A saturated acyclic organic compound containing C, H, and O can be written as:
Since it is saturated and acyclic, for a monofunctional oxygen-containing compound the hydrogen count follows the saturated pattern. We will determine the exact formula from the mass percentage ratios.
- Use the given mass percentage ratio of C and H
Given:
For formula ,
- mass of C
- mass of H
- mass of O
So,
- Use the given mass percentage ratio of C and O
Given:
So,
Cross-multiplying:
Thus,
and from above,
Hence empirical formula is:
- Use saturation condition
For a saturated acyclic compound, the general relation is:
for compounds with one oxygen atom such as alcohols/ethers, because oxygen does not affect hydrogen deficiency.
So if the formula is , compare with ratio-derived formula:
Equating hydrogens:
Therefore,
Check:
- C mass
- H mass
- O mass
Then:
Correct.
- Write combustion reaction
For one mole of :
Count oxygen atoms on RHS:
- from : O atoms
- from : O atoms
Total oxygen atoms needed on RHS
Compound already contains oxygen atoms, so oxygen atoms needed from :
Thus,
So, 1 mole of compound requires:
For 2 moles of compound:
- Final answer
The moles of required for complete combustion of 2 moles of is:
More from Some Basic Concepts of Chemistry
- The mole fraction of glucose ( ) in an aqueous binary solution is 0.1. The mass percentage of water in it, to the nearest integer, is .2020 · Numerical
- The volume strength of 8.9 M solution calculated at 273 K and 1 atm is . (R = 0.0821 L atm K-1 mol-1) (rounded off ot the nearest integer)2020 · Numerical
- The strengths of 5.6 volume hydrogen peroxide (of density 1 g/mL) in terms of mass percentage and molarity (M), respectively, are: (Take molar mass of hydrogen peroxide as 34 g/mol)2020 · MCQ
- 6.023 1022 molecules are present in 10 g of a substance 'x'. The molarity of a solution containing 5 g of substance 'x' in 2 L solution is × 10-32020 · Numerical
- The volume (in mL) of 0.1 N NaOH required to neutralise 10 mL of 0.1 N phosphinic acid is .2020 · Numerical
- A 20.0 mL solution containing 0.2 g impure reacts completely with 0.316 g of in acid solution. The purity of (in %) is (mol. wt. of = 34; mol. wt. of = 158)2020 · Numerical
- The mass of ammonia in grams produced when 2.8 kg of dinitrogen quantitatively reacts with 1 kg of dihydrogen is .2020 · Numerical
- Consider the following equations : 2 + xA + yB (in basic medium) 2 + 6 + 5 x'C + y'D + z'E (in acidic medium) The sum of the stoichiometric coefficients x, y, x', y', and z' for products…2020 · Numerical