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Some Basic Concepts of Chemistry question

2020 · 2 Sep · Shift 2 · Q2
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Some Basic Concepts of Chemistry question

2020 · 2 Sep · Shift 2 · Q2

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
The ratio of the mass percentages of ‘C & H’ and ‘C & O’ of a saturated acyclic organic compound ‘X’ are 4 : 1 and 3 : 4 respectively. Then, the moles of oxygen gas required for complete combustion of two moles of organic compound ‘X’ is ‾\underline{\hspace{2cm}}​.
Numerical answer
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Correct answer: 5

  1. Let the saturated acyclic compound be a hydroxy compound

A saturated acyclic organic compound containing C, H, and O can be written as:

CnH2n+2Om\mathrm{C_nH_{2n+2}O_m}Cn​H2n+2​Om​

Since it is saturated and acyclic, for a monofunctional oxygen-containing compound the hydrogen count follows the saturated pattern. We will determine the exact formula from the mass percentage ratios.


  1. Use the given mass percentage ratio of C and H

Given:

%C:%H=4:1\%C : \%H = 4:1%C:%H=4:1

For formula CxHyOz\mathrm{C_xH_yO_z}Cx​Hy​Oz​,

  • mass of C =12x= 12x=12x
  • mass of H =y= y=y
  • mass of O =16z= 16z=16z

So,

12x:y=4:112x : y = 4 : 112x:y=4:1

12xy=4⇒y=3x\frac{12x}{y}=4 \Rightarrow y=3xy12x​=4⇒y=3x


  1. Use the given mass percentage ratio of C and O

Given:

%C:%O=3:4\%C : \%O = 3:4%C:%O=3:4

So,

12x:16z=3:412x : 16z = 3 : 412x:16z=3:4

12x16z=34\frac{12x}{16z} = \frac{3}{4}16z12x​=43​

Cross-multiplying:

48x=48z⇒x=z48x = 48z \Rightarrow x=z48x=48z⇒x=z

Thus,

z=xz=xz=x

and from above,

y=3xy=3xy=3x

Hence empirical formula is:

CxH3xOx=(CH3O)x\mathrm{C_xH_{3x}O_x} = (\mathrm{CH_3O})_xCx​H3x​Ox​=(CH3​O)x​


  1. Use saturation condition

For a saturated acyclic compound, the general relation is:

H=2C+2H = 2C + 2H=2C+2

for compounds with one oxygen atom such as alcohols/ethers, because oxygen does not affect hydrogen deficiency.

So if the formula is CnH2n+2O\mathrm{C_nH_{2n+2}O}Cn​H2n+2​O, compare with ratio-derived formula:

CnH3nOn\mathrm{C_nH_{3n}O_n}Cn​H3n​On​

Equating hydrogens:

3n=2n+23n = 2n + 23n=2n+2

n=2n=2n=2

Therefore,

X=C2H6O2\boxed{\mathrm{X=C_2H_6O_2}}X=C2​H6​O2​​

Check:

  • C mass =24=24=24
  • H mass =6=6=6
  • O mass =32=32=32

Then:

C:H=24:6=4:1C:H = 24:6 = 4:1C:H=24:6=4:1

C:O=24:32=3:4C:O = 24:32 = 3:4C:O=24:32=3:4

Correct.


  1. Write combustion reaction

For one mole of C2H6O2\mathrm{C_2H_6O_2}C2​H6​O2​:

C2H6O2+aO2→2CO2+3H2O\mathrm{C_2H_6O_2 + aO_2 \rightarrow 2CO_2 + 3H_2O}C2​H6​O2​+aO2​→2CO2​+3H2​O

Count oxygen atoms on RHS:

  • from 2CO22CO_22CO2​: 444 O atoms
  • from 3H2O3H_2O3H2​O: 333 O atoms

Total oxygen atoms needed on RHS =7=7=7

Compound already contains 222 oxygen atoms, so oxygen atoms needed from O2\mathrm{O_2}O2​:

7−2=57-2=57−2=5

Thus,

a=52a=\frac{5}{2}a=25​

So, 1 mole of compound requires:

52 moles of O2\frac{5}{2}\text{ moles of }O_225​ moles of O2​

For 2 moles of compound:

2×52=52 \times \frac{5}{2} = 52×25​=5


  1. Final answer

The moles of O2\mathrm{O_2}O2​ required for complete combustion of 2 moles of X\mathrm{X}X is:

5\boxed{5}5​

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