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Some Basic Concepts of Chemistry question

2021 · 16 Mar · Shift 1 · Q18
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Some Basic Concepts of Chemistry question

2021 · 16 Mar · Shift 1 · Q18

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
2MnO4−+bC2O42−+cH+→xMn2++yCO2+zH2O2MnO_4^ - + b{C_2}O_4^{2 - } + c{H^ + } \to xM{n^{2 + }} + yC{O_2} + z{H_2}O2MnO4−​+bC2​O42−​+cH+→xMn2++yCO2​+zH2​O If the above equation is balanced with integer coefficients, the value of c is ‾\underline{\hspace{2cm}}​. (Round off to the Nearest Integer).
Numerical answer
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Correct answer: 16

  1. We need to balance the redox reaction:

2MnO4−+bC2O42−+cH+→xMn2++yCO2+zH2O2\text{MnO}_4^- + b\text{C}_2\text{O}_4^{2-} + c\text{H}^+ \to x\text{Mn}^{2+} + y\text{CO}_2 + z\text{H}_2\text{O}2MnO4−​+bC2​O42−​+cH+→xMn2++yCO2​+zH2​O

We are asked to find the coefficient ccc of H+\text{H}^+H+.

  1. Use the ion-electron method in acidic medium.

Oxidation half-reaction

Oxalate is oxidized to carbon dioxide:

C2O42−→2CO2+2e−\text{C}_2\text{O}_4^{2-} \to 2\text{CO}_2 + 2e^-C2​O42−​→2CO2​+2e−

Reduction half-reaction

Permanganate is reduced to Mn2+\text{Mn}^{2+}Mn2+ in acidic medium:

MnO4−+8H++5e−→Mn2++4H2O\text{MnO}_4^- + 8\text{H}^+ + 5e^- \to \text{Mn}^{2+} + 4\text{H}_2\text{O}MnO4−​+8H++5e−→Mn2++4H2​O

  1. Equalize electrons.
  • Oxidation half gives 2e−2e^-2e−
  • Reduction half needs 5e−5e^-5e−

LCM of 2 and 5 is 10.

So multiply:

  • oxidation half by 5
  • reduction half by 2

Thus,

5C2O42−→10CO2+10e−5\text{C}_2\text{O}_4^{2-} \to 10\text{CO}_2 + 10e^-5C2​O42−​→10CO2​+10e−

2MnO4−+16H++10e−→2Mn2++8H2O2\text{MnO}_4^- + 16\text{H}^+ + 10e^- \to 2\text{Mn}^{2+} + 8\text{H}_2\text{O}2MnO4−​+16H++10e−→2Mn2++8H2​O

  1. Add the two half-reactions:

2MnO4−+5C2O42−+16H+→2Mn2++10CO2+8H2O2\text{MnO}_4^- + 5\text{C}_2\text{O}_4^{2-} + 16\text{H}^+ \to 2\text{Mn}^{2+} + 10\text{CO}_2 + 8\text{H}_2\text{O}2MnO4−​+5C2​O42−​+16H+→2Mn2++10CO2​+8H2​O

  1. Compare with the given form:

2MnO4−+bC2O42−+cH+→xMn2++yCO2+zH2O2\text{MnO}_4^- + b\text{C}_2\text{O}_4^{2-} + c\text{H}^+ \to x\text{Mn}^{2+} + y\text{CO}_2 + z\text{H}_2\text{O}2MnO4−​+bC2​O42−​+cH+→xMn2++yCO2​+zH2​O

So,

c=16c = 16c=16

  1. Since this is already an integer, rounding to nearest integer still gives:

16\boxed{16}16​

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