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Some Basic Concepts of Chemistry question

2019 · 12 Apr · Shift 2 · Q15
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Some Basic Concepts of Chemistry question

2019 · 12 Apr · Shift 2 · Q15

JEE MainChemistrySome Basic Concepts of ChemistryMCQ+4 / −1
25 g of an unknown hydrocarbon upon burning produces 88 g of CO2CO_2CO2​ and 9 g of H2OH_2OH2​O. This unknown hydrocarbon contains :
  1. A
    18 g of carbon and 7 g of hydrogen
  2. B
    20 g of carbon and 5 g of hydrogen
  3. C
    22 g of carbon and 3 g of hydrogen
  4. D
    24 g of carbon and 1 g of hydrogen
View written solutionFree

Correct answer: D

  1. Find the mass of carbon from CO2CO_2CO2​ produced

From combustion, all carbon in the hydrocarbon becomes CO2CO_2CO2​.

Given: 88 g of CO288\,\text{g of } CO_288g of CO2​

Molar mass of CO2=44 g/molCO_2 = 44\,\text{g/mol}CO2​=44g/mol, so moles of CO2=8844=2\text{moles of } CO_2 = \frac{88}{44} = 2moles of CO2​=4488​=2

Each mole of CO2CO_2CO2​ contains 111 mole of carbon, so moles of carbon = 222.

Hence mass of carbon: mC=2×12=24 gm_C = 2 \times 12 = 24\,\text{g}mC​=2×12=24g

  1. Find the mass of hydrogen from H2OH_2OH2​O produced

All hydrogen in the hydrocarbon becomes H2OH_2OH2​O.

Given: 9 g of H2O9\,\text{g of } H_2O9g of H2​O

Molar mass of H2O=18 g/molH_2O = 18\,\text{g/mol}H2​O=18g/mol, so moles of H2O=918=0.5\text{moles of } H_2O = \frac{9}{18} = 0.5moles of H2​O=189​=0.5

Each mole of H2OH_2OH2​O contains 222 moles of hydrogen atoms, so moles of hydrogen atoms: 0.5×2=10.5 \times 2 = 10.5×2=1

Hence mass of hydrogen: mH=1×1=1 gm_H = 1 \times 1 = 1\,\text{g}mH​=1×1=1g

  1. Check total mass

mC+mH=24+1=25 gm_C + m_H = 24 + 1 = 25\,\text{g}mC​+mH​=24+1=25g

This matches the given mass of the hydrocarbon, so the composition is correct.

  1. Compare with options
  • A: 181818 g C and 777 g H ❌
  • B: 202020 g C and 555 g H ❌
  • C: 222222 g C and 333 g H ❌
  • D: 242424 g C and 111 g H ✅

Therefore, the unknown hydrocarbon contains 242424 g of carbon and 111 g of hydrogen.

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