JEE MainChemistrySome Basic Concepts of ChemistryMCQ+4 / −1
At 300 K and 1 atmospheric pressure, 10 mL of a hydrocarbon required 55 mL of for complete combustion, and 40 mL of is formed. The formula of the hydrocarbon is :
- A
- B
- C
- D
View written solutionFree
Correct answer: B
-
Let the hydrocarbon be .
-
Use the combustion equation
-
Use volume ratios At the same temperature and pressure, gaseous volumes are proportional to moles.
Given:
- hydrocarbon requires
- is formed
-
Find from volume From the equation, 1 volume of gives volumes of .
So,
Hence the hydrocarbon is of the form .
-
Find from volume From the equation, 1 volume of requires volumes of .
Therefore,
-
Thus the hydrocarbon formula is
-
Check options
- A: → not a hydrocarbon
- B: → correct
- C: → would need volumes of , not
- D: → would need volumes of , not
Hence, the correct answer is B: .
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