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Some Basic Concepts of Chemistry question

2019 · 10 Apr · Shift 1 · Q12
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Some Basic Concepts of Chemistry question

2019 · 10 Apr · Shift 1 · Q12

JEE MainChemistrySome Basic Concepts of ChemistryMCQ+4 / −1
At 300 K and 1 atmospheric pressure, 10 mL of a hydrocarbon required 55 mL of O2O_2O2​ for complete combustion, and 40 mL of CO2CO_2CO2​ is formed. The formula of the hydrocarbon is :
  1. A
    C4H7ClC_4H_7ClC4​H7​Cl
  2. B
    C4H6C_4H_6C4​H6​
  3. C
    C4H8C_4H_8C4​H8​
  4. D
    C4H10C_4H_{10}C4​H10​
View written solutionFree

Correct answer: B

  1. Let the hydrocarbon be CxHyC_xH_yCx​Hy​.

  2. Use the combustion equation CxHy+(x+y4)O2→xCO2+y2H2OC_xH_y + \left(x + \frac{y}{4}\right)O_2 \rightarrow xCO_2 + \frac{y}{2}H_2OCx​Hy​+(x+4y​)O2​→xCO2​+2y​H2​O

  3. Use volume ratios At the same temperature and pressure, gaseous volumes are proportional to moles.

    Given:

    • 10 mL10\ \text{mL}10 mL hydrocarbon requires 55 mL55\ \text{mL}55 mL O2O_2O2​
    • 40 mL40\ \text{mL}40 mL CO2CO_2CO2​ is formed
  4. Find xxx from CO2CO_2CO2​ volume From the equation, 1 volume of CxHyC_xH_yCx​Hy​ gives xxx volumes of CO2CO_2CO2​.

    So, x=4010=4x = \frac{40}{10} = 4x=1040​=4

    Hence the hydrocarbon is of the form C4HyC_4H_yC4​Hy​.

  5. Find yyy from O2O_2O2​ volume From the equation, 1 volume of CxHyC_xH_yCx​Hy​ requires (x+y4)\left(x + \frac{y}{4}\right)(x+4y​) volumes of O2O_2O2​.

    Therefore, 4+y4=5510=5.54 + \frac{y}{4} = \frac{55}{10} = 5.54+4y​=1055​=5.5

    y4=1.5\frac{y}{4} = 1.54y​=1.5

    y=6y = 6y=6

  6. Thus the hydrocarbon formula is C4H6C_4H_6C4​H6​

  7. Check options

    • A: C4H7ClC_4H_7ClC4​H7​Cl → not a hydrocarbon
    • B: C4H6C_4H_6C4​H6​ → correct
    • C: C4H8C_4H_8C4​H8​ → would need 4+8/4=64 + 8/4 = 64+8/4=6 volumes of O2O_2O2​, not 5.55.55.5
    • D: C4H10C_4H_{10}C4​H10​ → would need 4+10/4=6.54 + 10/4 = 6.54+10/4=6.5 volumes of O2O_2O2​, not 5.55.55.5

Hence, the correct answer is B: C4H6C_4H_6C4​H6​.

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