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Some Basic Concepts of Chemistry question

2019 · 9 Jan · Shift 2 · Q22
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Some Basic Concepts of Chemistry question

2019 · 9 Jan · Shift 2 · Q22

JEE MainChemistrySome Basic Concepts of ChemistryMCQ+4 / −1
For the following reaction, in the mass of water produced from 445 g of C57H110O6C_{57}H_{110}O_6C57​H110​O6​ is : 2C57H110O6C_{57}H_{110}O_6C57​H110​O6​(s) + 163 O2O_2O2​(g) →\to→ 114 CO2CO_2CO2​(g) + 110 H2OH_2OH2​O(l)
  1. A
    490 g
  2. B
    445 g
  3. C
    495 g
  4. D
    890 g
View written solutionFree

Correct answer: C

  1. Given reaction

2C57H110O6+163O2→114CO2+110H2O2C_{57}H_{110}O_6 + 163O_2 \rightarrow 114CO_2 + 110H_2O2C57​H110​O6​+163O2​→114CO2​+110H2​O

We need the mass of water formed from 445 g of C57H110O6C_{57}H_{110}O_6C57​H110​O6​.


  1. Find molar mass of C57H110O6C_{57}H_{110}O_6C57​H110​O6​

Using C=12C=12C=12, H=1H=1H=1, O=16O=16O=16:

M=57(12)+110(1)+6(16)M = 57(12) + 110(1) + 6(16)M=57(12)+110(1)+6(16)

=684+110+96=890 g mol−1= 684 + 110 + 96 = 890 \text{ g mol}^{-1}=684+110+96=890 g mol−1

So,

1 mol of C57H110O6=890 g1 \text{ mol of } C_{57}H_{110}O_6 = 890 \text{ g}1 mol of C57​H110​O6​=890 g

Therefore,

445 g=445890=0.5 mol445 \text{ g} = \frac{445}{890} = 0.5 \text{ mol}445 g=890445​=0.5 mol


  1. Use stoichiometry from balanced equation

From the reaction:

2 mol C57H110O6→110 mol H2O2 \text{ mol } C_{57}H_{110}O_6 \rightarrow 110 \text{ mol } H_2O2 mol C57​H110​O6​→110 mol H2​O

So,

1 mol C57H110O6→55 mol H2O1 \text{ mol } C_{57}H_{110}O_6 \rightarrow 55 \text{ mol } H_2O1 mol C57​H110​O6​→55 mol H2​O

Hence,

0.5 mol C57H110O6→0.5×55=27.5 mol H2O0.5 \text{ mol } C_{57}H_{110}O_6 \rightarrow 0.5 \times 55 = 27.5 \text{ mol } H_2O0.5 mol C57​H110​O6​→0.5×55=27.5 mol H2​O


  1. Convert moles of water to mass

Molar mass of water:

M(H2O)=18 g mol−1M(H_2O)=18 \text{ g mol}^{-1}M(H2​O)=18 g mol−1

Mass of water formed:

27.5×18=495 g27.5 \times 18 = 495 \text{ g}27.5×18=495 g


  1. Check options
  • A: 490490490 g
  • B: 445445445 g
  • C: 495495495 g
  • D: 890890890 g

So the correct option is:

C: 495 g\boxed{\text{C: }495\text{ g}}C: 495 g​


  1. Comparison with stored answer

Stored correct answer: C

Our derived answer: C

They match.

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