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Solutions question

2019 · 12 Jan · Shift 1 · Q13
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Solutions question

2019 · 12 Jan · Shift 1 · Q13

JEE MainChemistrySolutionsMCQ+4 / −1
Freezing point of a 4% aqueous solution of X is equal to freezing point of 12% aqueous solution of Y. If molecular weight of X is A, then molecular weight of Y is -
  1. A
    4A
  2. B
    2A
  3. C
    3A
  4. D
    A
View written solutionFree

Correct answer: C

  1. Use freezing point depression relation

For dilute solutions, ΔTf=iKfm\Delta T_f = iK_f mΔTf​=iKf​m

Since both are aqueous solutions, the solvent is same, so KfK_fKf​ is same. Assuming both solutes are non-electrolytes, i=1i=1i=1.

Given that the freezing points are equal, their depressions in freezing point are equal: ΔTf1=ΔTf2\Delta T_{f1} = \Delta T_{f2}ΔTf1​=ΔTf2​ So, m1=m2m_1 = m_2m1​=m2​


  1. Interpret percentage composition

A 4% aqueous solution of XXX means:

  • 444 g of XXX in 100100100 g of solution
  • Hence, water =96= 96=96 g =0.096= 0.096=0.096 kg

Moles of XXX: 4A\frac{4}{A}A4​

Molality of XXX: m1=4/A0.096m_1 = \frac{4/A}{0.096}m1​=0.0964/A​


  1. For 12% aqueous solution of YYY

A 12% aqueous solution of YYY means:

  • 121212 g of YYY in 100100100 g of solution
  • Hence, water =88= 88=88 g =0.088= 0.088=0.088 kg

Let molecular weight of Y=MY = MY=M.

Moles of YYY: 12M\frac{12}{M}M12​

Molality of YYY: m2=12/M0.088m_2 = \frac{12/M}{0.088}m2​=0.08812/M​


  1. Equate molalities

4/A0.096=12/M0.088\frac{4/A}{0.096} = \frac{12/M}{0.088}0.0964/A​=0.08812/M​

40.096A=120.088M\frac{4}{0.096A} = \frac{12}{0.088M}0.096A4​=0.088M12​

Cross-multiplying: 4×0.088M=12×0.096A4 \times 0.088 M = 12 \times 0.096 A4×0.088M=12×0.096A

0.352M=1.152A0.352M = 1.152A0.352M=1.152A

M=1.1520.352AM = \frac{1.152}{0.352}AM=0.3521.152​A

M=3.27A≈3AM = 3.27A \approx 3AM=3.27A≈3A


  1. Choose nearest option

Thus the molecular weight of YYY is approximately: 3A\boxed{3A}3A​

So, the correct option is C.

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