JEE MainChemistrySolutionsMCQ+4 / −1
Freezing point of a 4% aqueous solution of X is equal to freezing point of 12% aqueous solution of Y. If molecular weight of X is A, then molecular weight of Y is -
- A4A
- B2A
- C3A
- DA
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Correct answer: C
- Use freezing point depression relation
For dilute solutions,
Since both are aqueous solutions, the solvent is same, so is same. Assuming both solutes are non-electrolytes, .
Given that the freezing points are equal, their depressions in freezing point are equal: So,
- Interpret percentage composition
A 4% aqueous solution of means:
- g of in g of solution
- Hence, water g kg
Moles of :
Molality of :
- For 12% aqueous solution of
A 12% aqueous solution of means:
- g of in g of solution
- Hence, water g kg
Let molecular weight of .
Moles of :
Molality of :
- Equate molalities
Cross-multiplying:
- Choose nearest option
Thus the molecular weight of is approximately:
So, the correct option is C.
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