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Redox Reactions question

2024 · 4 Apr · Shift 1 · Q22
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Redox Reactions question

2024 · 4 Apr · Shift 1 · Q22

JEE MainChemistryRedox ReactionsNumerical+4 / −1
Only 2 mL2 \mathrm{~mL}2 mL of KMnO4\mathrm{KMnO}_4KMnO4​ solution of unknown molarity is required to reach the end point of a titration of 20 mL20 \mathrm{~mL}20 mL of oxalic acid (2M)(2 \mathrm{M})(2M) in acidic medium. The molarity of KMnO4\mathrm{KMnO}_4KMnO4​ solution should be ‾\underline{\hspace{2cm}}​ M.
Numerical answer
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Correct answer: 8

  1. Write the balanced redox reaction in acidic medium

2 MnO4−+5 H2C2O4+6 H+→2 Mn2++10 CO2+8 H2O2\,\mathrm{MnO_4^-} + 5\,\mathrm{H_2C_2O_4} + 6\,\mathrm{H^+} \rightarrow 2\,\mathrm{Mn^{2+}} + 10\,\mathrm{CO_2} + 8\,\mathrm{H_2O}2MnO4−​+5H2​C2​O4​+6H+→2Mn2++10CO2​+8H2​O

So, the mole ratio is:

KMnO4:H2C2O4=2:5\mathrm{KMnO_4} : \mathrm{H_2C_2O_4} = 2:5KMnO4​:H2​C2​O4​=2:5

  1. Calculate moles of oxalic acid used

Given:

  • Volume of oxalic acid =20 mL=0.020 L= 20\,\mathrm{mL} = 0.020\,\mathrm{L}=20mL=0.020L
  • Molarity of oxalic acid =2 M= 2\,\mathrm{M}=2M

Hence,

n(H2C2O4)=M×V=2×0.020=0.040 moln(\mathrm{H_2C_2O_4}) = M \times V = 2 \times 0.020 = 0.040\,\mathrm{mol}n(H2​C2​O4​)=M×V=2×0.020=0.040mol

  1. Use stoichiometric ratio to find moles of KMnO4\mathrm{KMnO_4}KMnO4​

From the balanced equation,

n(KMnO4)n(H2C2O4)=25\frac{n(\mathrm{KMnO_4})}{n(\mathrm{H_2C_2O_4})} = \frac{2}{5}n(H2​C2​O4​)n(KMnO4​)​=52​

So,

n(KMnO4)=25×0.040=0.016 moln(\mathrm{KMnO_4}) = \frac{2}{5} \times 0.040 = 0.016\,\mathrm{mol}n(KMnO4​)=52​×0.040=0.016mol

  1. Calculate molarity of KMnO4\mathrm{KMnO_4}KMnO4​ solution

Given volume of KMnO4\mathrm{KMnO_4}KMnO4​ used:

2 mL=0.002 L2\,\mathrm{mL} = 0.002\,\mathrm{L}2mL=0.002L

Therefore,

M=nV=0.0160.002=8 MM = \frac{n}{V} = \frac{0.016}{0.002} = 8\,\mathrm{M}M=Vn​=0.0020.016​=8M

  1. Final answer

8\boxed{8}8​

This matches the stored correct answer.

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