JEE MainChemistryPractical Organic ChemistryNumerical+4 / −1
In the sulphur estimation, 0.471 g of an organic compound gave 1.44 g of barium sulphate. The percentage of sulphur in the compound is %. (Nearest integer) (Atomic Mass of Ba = 137 u)
Numerical answer
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Correct answer: 42
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Principle of sulphur estimation
In Carius method, sulphur present in the organic compound is converted into sulphate and finally precipitated as barium sulphate, . -
Molar mass of
Given atomic masses:
, , -
Mass of sulphur in of
In of , mass of sulphur .Therefore, in of ,
-
Percentage of sulphur in the compound
Mass of organic compound -
Nearest integer
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