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Practical Organic Chemistry question

2021 · 26 Aug · Shift 2 · Q13
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Practical Organic Chemistry question

2021 · 26 Aug · Shift 2 · Q13

JEE MainChemistryPractical Organic ChemistryNumerical+4 / −1
In the sulphur estimation, 0.471 g of an organic compound gave 1.44 g of barium sulphate. The percentage of sulphur in the compound is ‾\underline{\hspace{2cm}}​%. (Nearest integer) (Atomic Mass of Ba = 137 u)
Numerical answer
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Correct answer: 42

  1. Principle of sulphur estimation
    In Carius method, sulphur present in the organic compound is converted into sulphate and finally precipitated as barium sulphate, BaSO4\text{BaSO}_4BaSO4​.

  2. Molar mass of BaSO4\text{BaSO}_4BaSO4​
    Given atomic masses:
    Ba=137\text{Ba} = 137Ba=137, S=32\text{S} = 32S=32, O=16\text{O} = 16O=16

    M(BaSO4)=137+32+4×16=137+32+64=233M(\text{BaSO}_4)=137+32+4\times 16=137+32+64=233M(BaSO4​)=137+32+4×16=137+32+64=233

  3. Mass of sulphur in 1.44 g1.44\text{ g}1.44 g of BaSO4\text{BaSO}_4BaSO4​
    In 233 g233\text{ g}233 g of BaSO4\text{BaSO}_4BaSO4​, mass of sulphur =32 g=32\text{ g}=32 g.

    Therefore, in 1.44 g1.44\text{ g}1.44 g of BaSO4\text{BaSO}_4BaSO4​, Mass of S=32233×1.44\text{Mass of S} = \frac{32}{233}\times 1.44Mass of S=23332​×1.44

    Mass of S=46.08233≈0.1978 g\text{Mass of S} = \frac{46.08}{233} \approx 0.1978\text{ g}Mass of S=23346.08​≈0.1978 g

  4. Percentage of sulphur in the compound
    Mass of organic compound =0.471 g=0.471\text{ g}=0.471 g

    %S=0.19780.471×100\%\text{S} = \frac{0.1978}{0.471}\times 100%S=0.4710.1978​×100

    %S≈42.0%\%\text{S} \approx 42.0\%%S≈42.0%

  5. Nearest integer
    42\boxed{42}42​

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