JEE MainChemistryPractical Organic ChemistryNumerical+4 / −1
An organic compound is subjected to chlorination to get compound A using 5.0 g of chlorine. When 0.5 g of compound A is reacted with [Carius Method], the percentage of chlorine in compound A is when it forms 0.3849 g of . (Round off to the Nearest Integer) (Atomic masses of Ag and Cl are 107.87 and 35.5 respectively)
Numerical answer
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Correct answer: 19
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Use Carius method data to find mass of chlorine in the sample
The chlorine in compound is converted into .
Given:
- Mass of
- Atomic mass of
- Atomic mass of
So, molar mass of is
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Mass fraction of chlorine in
Therefore, mass of chlorine in of is
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Find percentage of chlorine in compound
The mass of compound taken is .
Hence,
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Round off to nearest integer
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About the given 5.0 g chlorine
The statement that compound is obtained using chlorine is not needed for calculating percentage of chlorine from the Carius method data. The percentage is determined directly from the formed.
Therefore, the percentage of chlorine in compound is .
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