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Practical Organic Chemistry question

2021 · 27 Jul · Shift 1 · Q17
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Practical Organic Chemistry question

2021 · 27 Jul · Shift 1 · Q17

JEE MainChemistryPractical Organic ChemistryNumerical+4 / −1
An organic compound is subjected to chlorination to get compound A using 5.0 g of chlorine. When 0.5 g of compound A is reacted with AgNO3AgNO_3AgNO3​ [Carius Method], the percentage of chlorine in compound A is ‾\underline{\hspace{2cm}}​ when it forms 0.3849 g of AgClAgClAgCl. (Round off to the Nearest Integer) (Atomic masses of Ag and Cl are 107.87 and 35.5 respectively)
Numerical answer
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Correct answer: 19

  1. Use Carius method data to find mass of chlorine in the sample

    The chlorine in compound AAA is converted into AgClAgClAgCl.

    Given:

    • Mass of AgCl=0.3849 gAgCl = 0.3849\,\text{g}AgCl=0.3849g
    • Atomic mass of Ag=107.87Ag = 107.87Ag=107.87
    • Atomic mass of Cl=35.5Cl = 35.5Cl=35.5

    So, molar mass of AgClAgClAgCl is 107.87+35.5=143.37107.87 + 35.5 = 143.37107.87+35.5=143.37

  2. Mass fraction of chlorine in AgClAgClAgCl

    Mass fraction of Cl in AgCl=35.5143.37\text{Mass fraction of Cl in } AgCl = \frac{35.5}{143.37}Mass fraction of Cl in AgCl=143.3735.5​

    Therefore, mass of chlorine in 0.3849 g0.3849\,\text{g}0.3849g of AgClAgClAgCl is mCl=0.3849×35.5143.37m_{Cl} = 0.3849 \times \frac{35.5}{143.37}mCl​=0.3849×143.3735.5​

    mCl≈0.0953 gm_{Cl} \approx 0.0953\,\text{g}mCl​≈0.0953g

  3. Find percentage of chlorine in compound AAA

    The mass of compound AAA taken is 0.5 g0.5\,\text{g}0.5g.

    Hence, %Cl=0.09530.5×100\%Cl = \frac{0.0953}{0.5} \times 100%Cl=0.50.0953​×100

    %Cl≈19.06%\%Cl \approx 19.06\%%Cl≈19.06%

  4. Round off to nearest integer

    19\boxed{19}19​

  5. About the given 5.0 g chlorine

    The statement that compound AAA is obtained using 5.0 g5.0\,\text{g}5.0g chlorine is not needed for calculating percentage of chlorine from the Carius method data. The percentage is determined directly from the AgClAgClAgCl formed.

Therefore, the percentage of chlorine in compound AAA is 19%\boxed{19\%}19%​.

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