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The number of moles of , that will be utilized in Dumas method for estimation nitrogen in a sample of 57.5 g of N, N-dimethylaminopentane is 10 2. (Nearest integer)
Numerical answer
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Correct answer: 1125
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Find the molecular formula of -dimethylaminopentane.
Pentyl group attached to nitrogen:
Two methyl groups on nitrogen:
So total formula is:
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Find molar mass of :
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Moles of compound in :
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Combustion equation in Dumas method
In Dumas method, the organic compound is heated with excess . Carbon forms , hydrogen forms , and nitrogen is liberated as .
Let:
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Balance oxygen atoms on products side:
Oxygen needed for :
Oxygen needed for :
Total oxygen atoms needed:
Hence,
So,
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Moles of required for mol compound:
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The question expresses answer as:
Write mol in this form:
Therefore, the required integer is:
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Comparison with stored answer
Derived answer =
Stored correct answer =
Hence, they agree.
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