JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The correct order of electron affinity is :
- AF > Cl > O
- BF > O > Cl
- CCl > F > O
- DO > F > Cl
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Correct answer: C
-
Recall the trend of electron affinity
Electron affinity generally becomes more negative across a period and less negative down a group. However, there are important exceptions due to very small atomic size and electron-electron repulsion. -
Compare chlorine and fluorine
Although fluorine is above chlorine in Group 17, chlorine has higher electron affinity than fluorine.
- For fluorine: the added electron enters the very compact orbital, where repulsion is high.
- For chlorine: the added electron enters the larger orbital, where repulsion is less.
So,
- Compare fluorine and oxygen
Both are in the second period, and halogens generally have higher electron affinity than chalcogens because halogens need one electron to attain noble gas configuration.
Thus,
- Combine the comparisons
From the above,
- Check options
- A: ❌
- B: ❌
- C: ✅
- D: ❌
Therefore, the correct order of electron affinity is
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