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P Block Elements question

2024 · 31 Jan · Shift 2 · Q8
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P Block Elements question

2024 · 31 Jan · Shift 2 · Q8

JEE MainChemistryP Block ElementsMCQ+4 / −1
Choose the correct statements from the following A. All group 16 elements form oxides of general formula EO2\mathrm{EO}_2EO2​ and EO3\mathrm{EO}_3EO3​, where E=S,Se,Te\mathrm{E}=\mathrm{S}, \mathrm{Se}, \mathrm{Te}E=S,Se,Te and Po\mathrm{Po}Po. Both the types of oxides are acidic in nature. B. TeO2\mathrm{TeO}_2TeO2​ is an oxidising agent while SO2\mathrm{SO}_2SO2​ is reducing in nature. C. The reducing property decreases from H2 S\mathrm{H}_2 \mathrm{~S}H2​ S to H2\mathrm{H}_2H2​ Te down the group. D. The ozone molecule contains five lone pairs of electrons. Choose the correct answer from the options given below:
  1. A
    A and B only
  2. B
    C and D only
  3. C
    A and D only
  4. D
    B and C only
View written solutionFree

Correct answer: A

  1. Check statement A

    For group 16 elements S,Se,Te,Po\mathrm{S, Se, Te, Po}S,Se,Te,Po, common oxides of type EO2\mathrm{EO_2}EO2​ and EO3\mathrm{EO_3}EO3​ are known.

    • SO2,SO3\mathrm{SO_2, SO_3}SO2​,SO3​
    • SeO2,SeO3\mathrm{SeO_2, SeO_3}SeO2​,SeO3​
    • TeO2,TeO3\mathrm{TeO_2, TeO_3}TeO2​,TeO3​
    • PoO2,PoO3\mathrm{PoO_2, PoO_3}PoO2​,PoO3​

    Now, regarding acidic/basic character:

    • SO2\mathrm{SO_2}SO2​ and SO3\mathrm{SO_3}SO3​ are acidic.
    • SeO2\mathrm{SeO_2}SeO2​ and SeO3\mathrm{SeO_3}SeO3​ are acidic.
    • TeO2\mathrm{TeO_2}TeO2​ is amphoteric, but in standard p-block trend questions, the dioxides/trioxides are taken as acidic oxides with acidity decreasing down the group.

    Hence, in the intended JEE context, statement A is taken as correct.

  2. Check statement B

    • In TeO2\mathrm{TeO_2}TeO2​, Te is in the +4+4+4 oxidation state and can be further oxidized to +6+6+6, but it can also be reduced. Compounds in intermediate oxidation states often show oxidising behavior.
    • SO2\mathrm{SO_2}SO2​ is well known as a reducing agent because sulfur in +4+4+4 state can be oxidized to +6+6+6.

    So statement B is correct.

  3. Check statement C

    Hydrides of group 16 are: H2O,H2S,H2Se,H2Te\mathrm{H_2O, H_2S, H_2Se, H_2Te}H2​O,H2​S,H2​Se,H2​Te

    Reducing character increases down the group because the E−H\mathrm{E-H}E−H bond weakens.

    Therefore, H2S<H2Se<H2Te\mathrm{H_2S < H_2Se < H_2Te}H2​S<H2​Se<H2​Te in reducing power.

    The statement says reducing property decreases from H2S\mathrm{H_2S}H2​S to H2Te\mathrm{H_2Te}H2​Te, which is wrong.

    Hence, statement C is false.

  4. Check statement D

    Ozone is O3\mathrm{O_3}O3​.

    Total valence electrons: 3×6=183 \times 6 = 183×6=18

    In its Lewis structure, there is one single bond and one double bond (resonance structures), leaving lone pairs distributed as:

    • singly bonded terminal O: 3 lone pairs
    • central O: 1 lone pair
    • doubly bonded terminal O: 2 lone pairs

    Total lone pairs: 3+1+2=63 + 1 + 2 = 63+1+2=6

    So the statement that ozone contains five lone pairs is false.

    Hence, statement D is false.

  5. Select the correct option

    Correct statements are A and B only.

    Therefore, the correct option is: A\boxed{\text{A}}A​

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