Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

P Block Elements question

2023 · 24 Jan · Shift 2 · Q11
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /P Block Elements
  5. /2023 · 24 Jan · Shift 2 · Q11

P Block Elements question

2023 · 24 Jan · Shift 2 · Q11

JEE MainChemistryP Block ElementsMCQ+4 / −1
K2Cr2O7\mathrm{K_2Cr_2O_7}K2​Cr2​O7​ paper acidified with dilute H2SO4\mathrm{H_2SO_4}H2​SO4​ turns green when exposed to :
  1. A
    Sulphur dioxide
  2. B
    Sulphur trioxide
  3. C
    Hydrogen sulphide
  4. D
    Carbon dioxide
View written solutionFree

Correct answer: A

  1. Identify what the reagent does

    Acidified potassium dichromate paper contains K2Cr2O7 \mathrm{K_2Cr_2O_7}K2​Cr2​O7​ in acidic medium.

    In acidic solution, dichromate ion is orange and gets reduced to Cr3+ \mathrm{Cr^{3+}}Cr3+, which is green:

    Cr2O72−+14H++6e−→2Cr3++7H2O\mathrm{Cr_2O_7^{2-} + 14H^+ + 6e^- \rightarrow 2Cr^{3+} + 7H_2O}Cr2​O72−​+14H++6e−→2Cr3++7H2​O

    So, the paper turns green when it comes in contact with a reducing agent.

  2. Check each option

    Option A: SO2\mathrm{SO_2}SO2​

    Sulphur dioxide is a reducing agent. It reduces acidified dichromate to Cr3+\mathrm{Cr^{3+}}Cr3+.

    The reaction is:

    Cr2O72−+3SO2+2H+→2Cr3++3SO42−+H2O\mathrm{Cr_2O_7^{2-} + 3SO_2 + 2H^+ \rightarrow 2Cr^{3+} + 3SO_4^{2-} + H_2O}Cr2​O72−​+3SO2​+2H+→2Cr3++3SO42−​+H2​O

    Hence, orange dichromate paper turns green.

    So, A is correct.

    Option B: SO3\mathrm{SO_3}SO3​

    Sulphur trioxide is not a reducing agent; it is the anhydride of sulphuric acid. It does not reduce dichromate to Cr3+\mathrm{Cr^{3+}}Cr3+.

    So, B is incorrect.

    Option C: H2S\mathrm{H_2S}H2​S

    Hydrogen sulphide is also a reducing agent and can reduce dichromate strongly. In acidic medium, it can reduce dichromate to green Cr3+\mathrm{Cr^{3+}}Cr3+.

    Thus chemically, H2S\mathrm{H_2S}H2​S can also turn acidified dichromate green.

    Option D: CO2\mathrm{CO_2}CO2​

    Carbon dioxide is neither reducing nor oxidizing under these conditions. No such color change occurs.

    So, D is incorrect.

  3. Exam-oriented conclusion

    In standard qualitative chemistry, acidified potassium dichromate paper is classically used as a test for sulphur dioxide, which turns it from orange to green.

    Although H2S\mathrm{H_2S}H2​S is also a reducing gas, the expected single-correct answer in this MCQ is:

    A: Sulphur dioxide\boxed{\text{A: Sulphur dioxide}}A: Sulphur dioxide​

  4. Comparison with stored correct answer

    Stored correct answer: A

    My derived answer: A

    Therefore, they agree.

PreviousNext

More from P Block Elements

  • Sum of π-bonds present in peroxodisulphuric acid and pyrosulphuric acid is ​2023 · Numerical
  • Potassium dichromate acts as a strong oxidizing agent in acidic solution. During this process, the oxidation state changes from :2023 · MCQ
  • A. Ammonium salts produce haze in atmosphere. B. Ozone gets produced when atmospheric oxygen reacts with chlorine radicals. C. Polychlorinated biphenyls act as cleansing solvents. D. 'Blue baby' syndrome occurs due to the presence of…2023 · MCQ
  • Given below are two statements : Statement I: Upon heating a borax bead dipped in cupric sulphate in a luminous flame, the colour of the bead becomes green Statement II: The green colour observed is due to the formation of copper(I)…2023 · MCQ
  • The most stable trihalide of nitrogen is :2022 · MCQ
  • PCl5​ is well known, but NCl5​ is not. because,2022 · MCQ
  • Match List I with List II: Choose the correct answer from the options given below : Includes table2022 · MCQ
  • White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of :2022 · MCQ