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P Block Elements question

2022 · 24 Jun · Shift 1 · Q6
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P Block Elements question

2022 · 24 Jun · Shift 1 · Q6

JEE MainChemistryP Block ElementsMCQ+4 / −1
The most stable trihalide of nitrogen is :
  1. A
    NF3NF_3NF3​
  2. B
    NCl3NCl_3NCl3​
  3. C
    NBr3NBr_3NBr3​
  4. D
    NI3NI_3NI3​
View written solutionFree

Correct answer: A

  1. We compare the stability of nitrogen trihalides NX3NX_3NX3​ where X=F,Cl,Br,IX=F,Cl,Br,IX=F,Cl,Br,I.

  2. Key factor: bond strength of the N−XN-XN−X bond

    • Stability of NX3NX_3NX3​ depends largely on how strong the N−XN-XN−X bonds are.
    • Because nitrogen is very small, it forms the strongest bond with the smallest halogen, fluorine.
    • As we move down the group: N−F>N−Cl>N−Br>N−IN-F > N-Cl > N-Br > N-IN−F>N−Cl>N−Br>N−I in bond strength.
  3. Effect of size mismatch and repulsion

    • In NCl3NCl_3NCl3​, NBr3NBr_3NBr3​, and especially NI3NI_3NI3​, the larger halogen atoms lead to poorer overlap with nitrogen orbitals.
    • This makes the bonds weaker and the compounds less stable.
    • NI3NI_3NI3​ is extremely unstable and explosive.
  4. Why NF3NF_3NF3​ is most stable

    • N−FN-FN−F bond is strongest due to effective orbital overlap.
    • Although fluorine is highly electronegative, NF3NF_3NF3​ is a well-known stable compound.
    • Thus among all nitrogen trihalides, NF3NF_3NF3​ is the most stable.
  5. Option-wise check

    • A: NF3NF_3NF3​ — most stable ✅
    • B: NCl3NCl_3NCl3​ — less stable than NF3NF_3NF3​
    • C: NBr3NBr_3NBr3​ — even less stable
    • D: NI3NI_3NI3​ — least stable, highly explosive

Therefore, the most stable trihalide of nitrogen is: NF3\boxed{NF_3}NF3​​

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