JEE MainChemistryP Block ElementsMCQ+4 / −1
The most stable trihalide of nitrogen is :
- A
- B
- C
- D
View written solutionFree
Correct answer: A
-
We compare the stability of nitrogen trihalides where .
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Key factor: bond strength of the bond
- Stability of depends largely on how strong the bonds are.
- Because nitrogen is very small, it forms the strongest bond with the smallest halogen, fluorine.
- As we move down the group: in bond strength.
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Effect of size mismatch and repulsion
- In , , and especially , the larger halogen atoms lead to poorer overlap with nitrogen orbitals.
- This makes the bonds weaker and the compounds less stable.
- is extremely unstable and explosive.
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Why is most stable
- bond is strongest due to effective orbital overlap.
- Although fluorine is highly electronegative, is a well-known stable compound.
- Thus among all nitrogen trihalides, is the most stable.
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Option-wise check
- A: — most stable ✅
- B: — less stable than
- C: — even less stable
- D: — least stable, highly explosive
Therefore, the most stable trihalide of nitrogen is:
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