- ABoth Statement I and Statement II are false
- BStatement I is false but Statement II is true
- CStatement I is true but Statement II is false
- DBoth Statement I and Statement II are true
View written solutionFree
Correct answer: D
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Analyze Statement (I): reactions are stereospecific
In an reaction, the nucleophile attacks the carbon atom from the backside of the leaving group.
This causes Walden inversion at the chiral center.
So, if the substrate is optically active and has a chiral center, the configuration changes in a definite way: (depending on priority order after substitution).
Thus, the reaction is stereospecific because a given stereoisomeric reactant gives a specific stereoisomeric product.
Therefore, Statement (I) is true.
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Analyze Statement (II): reactions generally give racemic mixtures
In an reaction, the leaving group first departs to form a planar carbocation intermediate.
Since the carbocation is planar, the nucleophile can attack from either side:
- front side attack
- back side attack
Hence, both enantiomers are formed, and the product is generally a racemic mixture (though often not perfectly 50:50 due to ion-pair effects, but generally racemization is observed).
Therefore, Statement (II) is true.
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Choose the correct option
Since both statements are true, the correct option is:
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Comparison with stored answer
Stored correct answer:
My derived answer also is , so they agree.
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