Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Hydrocarbons question

2024 · 30 Jan · Shift 1 · Q14
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Hydrocarbons
  5. /2024 · 30 Jan · Shift 1 · Q14

Hydrocarbons question

2024 · 30 Jan · Shift 1 · Q14

JEE MainChemistryHydrocarbonsMCQ+4 / −1
In the given reactions, identify the reagent A and reagent B. JEE Main 2024 (Online) 30th January Morning Shift Chemistry - Hydrocarbons Question 29 English
  1. A
    A−CrO3 B−CrO3\mathrm{A}-\mathrm{CrO}_3 \quad \mathrm{~B}-\mathrm{CrO}_3A−CrO3​ B−CrO3​
  2. B
    A−CrO3 B−CrO2Cl2\mathrm{A}-\mathrm{CrO}_3 \quad \mathrm{~B}-\mathrm{CrO}_2 \mathrm{Cl}_2A−CrO3​ B−CrO2​Cl2​
  3. C
    A- CrO2Cl2 B−CrO3\mathrm{CrO}_2 \mathrm{Cl}_2 \quad \mathrm{~B}-\mathrm{CrO}_3CrO2​Cl2​ B−CrO3​
  4. D
    A−CrO2Cl2 B−CrO2Cl2\mathrm{A}-\mathrm{CrO}_2 \mathrm{Cl}_2 \quad \mathrm{~B}-\mathrm{CrO}_2 \mathrm{Cl}_2A−CrO2​Cl2​ B−CrO2​Cl2​
View written solutionFree

Correct answer: B

  1. The key reagents involved are:

    • CrO3\mathrm{CrO_3}CrO3​: a strong oxidizing agent, used for oxidation of side chains/allied benzylic oxidation under suitable conditions.
    • CrO2Cl2\mathrm{CrO_2Cl_2}CrO2​Cl2​: chromyl chloride, specifically known for the Etard reaction, which oxidizes the benzylic methyl group of an aromatic ring to an aldehyde.
  2. To identify AAA and BBB, we use the characteristic reaction of chromyl chloride:

    Ar−CH3→CrO2Cl2Ar−CHO\mathrm{Ar-CH_3} \xrightarrow[ ]{CrO_2Cl_2} \mathrm{Ar-CHO}Ar−CH3​CrO2​Cl2​​Ar−CHO

    So whenever the conversion is from a methyl-substituted aromatic compound to the corresponding aldehyde, the reagent must be CrO2Cl2\mathrm{CrO_2Cl_2}CrO2​Cl2​.

  3. A stronger oxidation with CrO3\mathrm{CrO_3}CrO3​ generally takes benzylic side chains further to the carboxylic acid:

    Ar−CH3→CrO3Ar−COOH\mathrm{Ar-CH_3} \xrightarrow[ ]{CrO_3} \mathrm{Ar-COOH}Ar−CH3​CrO3​​Ar−COOH

  4. Therefore:

    • The reagent giving aldehyde formation must be B=CrO2Cl2B = \mathrm{CrO_2Cl_2}B=CrO2​Cl2​.
    • The other oxidation corresponds to A=CrO3A = \mathrm{CrO_3}A=CrO3​.
  5. Hence the correct combination is:

    A=CrO3,B=CrO2Cl2A = \mathrm{CrO_3}, \qquad B = \mathrm{CrO_2Cl_2}A=CrO3​,B=CrO2​Cl2​

  6. This matches Option B.

PreviousNext

More from Hydrocarbons

  • Compound A formed in the following reaction reacts with B gives the product C. Find out A and B. Includes diagram2024 · MCQ
  • Products A and B formed in the following set of reactions are Includes diagram2024 · MCQ
  • Major product of the following reaction is - Includes diagram2024 · MCQ
  • But-2-yne is reacted separately with one mole of Hydrogen as shown below : A. A is more soluble than B. B. The boiling point & melting point of A are higher and lower than B respectively. C. A is more polar than B because dipole moment… Includes diagram2023 · MCQ
  • 'X' is : Includes diagram2023 · MCQ
  • Number of bromo derivatives obtained on treating ethane with excess of Br2​ in diffused sunlight is ​2023 · Numerical
  • In the following reaction, 'B' is Includes diagram2023 · MCQ
  • Find out the major product from the following reaction. Includes diagram2023 · MCQ