JEE MainChemistryHydrocarbonsMCQ+4 / −1
In the given reactions, identify the reagent A and reagent B. 

- A
- B
- CA-
- D
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Correct answer: B
-
The key reagents involved are:
- : a strong oxidizing agent, used for oxidation of side chains/allied benzylic oxidation under suitable conditions.
- : chromyl chloride, specifically known for the Etard reaction, which oxidizes the benzylic methyl group of an aromatic ring to an aldehyde.
-
To identify and , we use the characteristic reaction of chromyl chloride:
So whenever the conversion is from a methyl-substituted aromatic compound to the corresponding aldehyde, the reagent must be .
-
A stronger oxidation with generally takes benzylic side chains further to the carboxylic acid:
-
Therefore:
- The reagent giving aldehyde formation must be .
- The other oxidation corresponds to .
-
Hence the correct combination is:
-
This matches Option B.
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