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Hydrocarbons question

2024 · 9 Apr · Shift 2 · Q20
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  5. /2024 · 9 Apr · Shift 2 · Q20

Hydrocarbons question

2024 · 9 Apr · Shift 2 · Q20

JEE MainChemistryHydrocarbonsMCQ+4 / −1
The incorrect statement regarding ethyne is
  1. A
    The carbon - carbon bonds in ethyne is weaker than that in ethene
  2. B
    Both carbons are sp hybridised
  3. C
    The C−C\mathrm{C}-\mathrm{C}C−C bonds in ethyne is shorter than that in ethene
  4. D
    Ethyne is linear
View written solutionFree

Correct answer: A

  1. Write the structure and hybridisation of ethyne

    Ethyne is HC≡CH\mathrm{HC\equiv CH}HC≡CH.

    In ethyne, each carbon atom is spspsp-hybridised. Therefore, the molecule is linear with bond angle 180∘180^\circ180∘.

  2. Check each statement

    Option A:

    "The carbon-carbon bond in ethyne is weaker than that in ethene"

    • Ethyne has a triple bond C≡C\mathrm{C\equiv C}C≡C.
    • Ethene has a double bond C=C\mathrm{C=C}C=C.
    • A triple bond has higher bond dissociation energy than a double bond, so it is stronger, not weaker.

    Hence, Option A is incorrect.

    Option B:

    "Both carbons are spspsp hybridised"

    This is true for ethyne.

    Hence, Option B is correct.

    Option C:

    "The C−C\mathrm{C-C}C−C bond in ethyne is shorter than that in ethene"

    • Triple bond length << < double bond length.
    • So the C≡C\mathrm{C\equiv C}C≡C bond in ethyne is shorter than the C=C\mathrm{C=C}C=C bond in ethene.

    Hence, Option C is correct.

    Option D:

    "Ethyne is linear"

    Since each carbon is spspsp hybridised, the geometry is linear.

    Hence, Option D is correct.

  3. Conclusion

    The incorrect statement is: A\boxed{A}A​

  4. Comparison with stored correct answer

    Stored correct answer: AAA

    My derived answer matches the stored correct answer.

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