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Hydrocarbons question

2022 · 26 Jul · Shift 1 · Q6
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  5. /2022 · 26 Jul · Shift 1 · Q6

Hydrocarbons question

2022 · 26 Jul · Shift 1 · Q6

JEE MainChemistryHydrocarbonsMCQ+4 / −1
Cl∙+CH4→A+B\stackrel{\bullet}{\mathrm{Cl}}+\mathrm{CH}_{4} \rightarrow \mathrm{A}+\mathrm{B}Cl∙+CH4​→A+B A and B in the above atmospheric reaction step are :
  1. A
    C2H6\mathrm{C}_{2} \mathrm{H}_{6}C2​H6​ and Cl2\mathrm{Cl}_{2}Cl2​
  2. B
    C∙HCl2\stackrel{\bullet}{\mathrm{C}} \mathrm{HCl}_{2}C∙​HCl2​ and H2\mathrm{H}_{2}H2​
  3. C
    C∙H3\stackrel{\bullet}{\mathrm{C}}\mathrm{H}_{3}C∙​H3​ and HCl\mathrm{HCl}HCl
  4. D
    C2H6\mathrm{C}_{2} \mathrm{H}_{6}C2​H6​ and HCl\mathrm{HCl}HCl
View written solutionFree

Correct answer: C

  1. Identify the type of reaction

    The reaction is: \ceCl.+CH4−>A+B\ce{Cl^. + CH4 -> A + B}\ceCl.+CH4−>A+B

    A chlorine radical reacts with methane. This is a free-radical substitution propagation step.

  2. What does chlorine radical do to methane?

    A chlorine radical abstracts one hydrogen atom from methane: \ceCl.+CH4−>HCl+CH3.\ce{Cl^. + CH4 -> HCl + CH3^.}\ceCl.+CH4−>HCl+CH3.

    Here:

    • chlorine radical takes one H atom from methane,
    • methane becomes methyl radical, \ceCH3.\ce{CH3^.}\ceCH3.,
    • and \ceHCl\ce{HCl}\ceHCl is formed.
  3. Match with the options

    The products are: A=\ceCH3.,B=\ceHClA = \ce{CH3^.}, \quad B = \ce{HCl}A=\ceCH3.,B=\ceHCl

    This corresponds to Option C.

  4. Check other options briefly

    • A: \ceC2H6\ce{C2H6}\ceC2H6 and \ceCl2\ce{Cl2}\ceCl2 — not formed in this elementary step.
    • B: radical written is not correct for this step, and \ceH2\ce{H2}\ceH2 is not formed.
    • D: \ceC2H6\ce{C2H6}\ceC2H6 and \ceHCl\ce{HCl}\ceHCl — ethane is not formed directly here.

Therefore, the correct answer is C.

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