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Hydrocarbons question

2021 · 16 Mar · Shift 1 · Q10
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Hydrocarbons question

2021 · 16 Mar · Shift 1 · Q10

JEE MainChemistryHydrocarbonsMCQ+4 / −1
Which of the following is Lindlar catalyst?
  1. A
    Partially deactivated palladised charcoal
  2. B
    Zinc chloride and HCl
  3. C
    Sodium and Liquid NH3NH_3NH3​
  4. D
    Cold dilute solution of KMnO4KMnO_4KMnO4​
View written solutionFree

Correct answer: A

  1. Recall the definition of Lindlar catalyst

    Lindlar catalyst is a partially deactivated palladium catalyst used for the selective hydrogenation of alkynes to cis-alkenes.

    It is typically: Pd on CaCO3 or charcoal, poisoned with lead acetate/quinoline\text{Pd on } CaCO_3 \text{ or charcoal, poisoned with lead acetate/quinoline}Pd on CaCO3​ or charcoal, poisoned with lead acetate/quinoline

    So the key idea is: palladium catalyst in a partially deactivated form.

  2. Check each option

    Option A: Partially deactivated palladised charcoal

    This matches the description of Lindlar catalyst, since Lindlar catalyst is a poisoned/deactivated palladium catalyst.

    Hence, A is correct.


    Option B: Zinc chloride and HCl

    This is Lucas reagent, used in alcohol chemistry, not Lindlar catalyst.

    Hence, B is incorrect.


    Option C: Sodium and Liquid NH3NH_3NH3​

    This is the dissolving metal reduction system used to convert alkynes to trans-alkenes, not Lindlar catalyst.

    Hence, C is incorrect.


    Option D: Cold dilute solution of KMnO4KMnO_4KMnO4​

    This is Baeyer's reagent, used to test unsaturation and for oxidation, not Lindlar catalyst.

    Hence, D is incorrect.

  3. Final answer

    The correct option is: A\boxed{A}A​

  4. Comparison with stored correct answer

    Stored correct answer: A

    My derived answer: A

    Therefore, they agree.

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