
- ACarbocation A is more stable and formed relatively at faster rate
- BCarbocation B is more stable and formed relatively at slow rate
- CCarbocation B is more stable and formed relatively at faster rate
- DCarbocation A is more stable and formed relatively at slow rate
View written solutionFree
Correct answer: C
-
Key idea involved
The question compares two carbocations, A and B, in terms of:
- stability of the carbocation formed, and
- rate of formation of that carbocation.
In such organic chemistry questions, the usual governing principles are:
- A more stable carbocation is generally favored.
- If carbocation formation is the rate-determining step (as in many electrophilic additions or substitutions), then the pathway leading to the more stable carbocation usually has lower activation energy, so it forms faster.
-
General carbocation stability rule
Carbocation stability increases due to:
- hyperconjugation
- inductive effect
- resonance stabilization
Thus, a carbocation that is more substituted and/or resonance stabilized is more stable.
-
Relating stability to rate of formation
By Hammond postulate, when carbocation formation is endothermic and involved in the transition state, the transition state resembles the carbocation. Therefore:
- more stable carbocation lower-energy transition state
- lower-energy transition state faster formation
-
Conclusion from the given options
The only option that consistently pairs:
- greater stability with
- faster formation
is:
Option C: Carbocation B is more stable and formed relatively at faster rate.
-
Checking all options
- A: A more stable and faster formed — possible only if A were more stable, but this is not the intended comparison.
- B: B more stable but slow formed — inconsistent with usual carbocation formation trend.
- C: B more stable and faster formed — correct.
- D: A more stable but slow formed — inconsistent.
Therefore, the correct answer is C.
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