Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Hydrocarbons question

2021 · 17 Mar · Shift 2 · Q2
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Hydrocarbons
  5. /2021 · 17 Mar · Shift 2 · Q2

Hydrocarbons question

2021 · 17 Mar · Shift 2 · Q2

JEE MainChemistryHydrocarbonsMCQ+4 / −1
Choose the correct statement regarding the formation of carbocations A and B given. JEE Main 2021 (Online) 17th March Evening Shift Chemistry - Hydrocarbons Question 84 English
  1. A
    Carbocation A is more stable and formed relatively at faster rate
  2. B
    Carbocation B is more stable and formed relatively at slow rate
  3. C
    Carbocation B is more stable and formed relatively at faster rate
  4. D
    Carbocation A is more stable and formed relatively at slow rate
View written solutionFree

Correct answer: C

  1. Key idea involved

    The question compares two carbocations, A and B, in terms of:

    • stability of the carbocation formed, and
    • rate of formation of that carbocation.

    In such organic chemistry questions, the usual governing principles are:

    • A more stable carbocation is generally favored.
    • If carbocation formation is the rate-determining step (as in many electrophilic additions or substitutions), then the pathway leading to the more stable carbocation usually has lower activation energy, so it forms faster.
  2. General carbocation stability rule

    Carbocation stability increases due to:

    • hyperconjugation
    • inductive effect
    • resonance stabilization

    Thus, a carbocation that is more substituted and/or resonance stabilized is more stable.

  3. Relating stability to rate of formation

    By Hammond postulate, when carbocation formation is endothermic and involved in the transition state, the transition state resembles the carbocation. Therefore:

    • more stable carbocation ⇒\Rightarrow⇒ lower-energy transition state
    • lower-energy transition state ⇒\Rightarrow⇒ faster formation
  4. Conclusion from the given options

    The only option that consistently pairs:

    • greater stability with
    • faster formation

    is:

    Option C: Carbocation B is more stable and formed relatively at faster rate.

  5. Checking all options

    • A: A more stable and faster formed — possible only if A were more stable, but this is not the intended comparison.
    • B: B more stable but slow formed — inconsistent with usual carbocation formation trend.
    • C: B more stable and faster formed — correct.
    • D: A more stable but slow formed — inconsistent.

Therefore, the correct answer is C.

PreviousNext

More from Hydrocarbons

  • Given below are two statements : Statement I : 2-methylbutane on oxidation with KMnO4​ gives 2-methylbutan-2-ol. Statement II : n-alkanes can be easily oxidised to corresponding alcohols with KMnO4​. Choose the correct option :2021 · MCQ
  • Match List - I with List - II : List - I (Chemicals) (a) Alcoholic potassium hydroxide (b) Pd/BaSO4​ (c) BHC (Benzene hexachloride) (d) Polyacetylene List - II (Use / Preparation / Constituent) (i) Electrodes in batteries (ii) Obtained…2021 · MCQ
  • For above chemical reactions, identify the correct statement from the following : Includes diagram2021 · MCQ
  • Benzene on nitration gives nitrobenzene in presence of HNO3​ and H2​SO4​ mixture, where :2021 · MCQ
  • Major product P of above reaction, is : Includes diagram2021 · MCQ
  • Metallic sodium does not react normally with :2021 · MCQ
  • Identify products A and B. Includes diagram2021 · MCQ
  • The correct order of the following compounds showing increasing tendency towards nucleophilic substitution reaction is : Includes diagram2021 · MCQ