Choose the correct answer from the options given below:- A
- B
- C
- D
View written solutionFree
Correct answer: B
To determine the order of reactivity of haloarenes toward nucleophilic substitution with aqueous , we use the rule for nucleophilic aromatic substitution.
1. Key principle
In haloarenes, nucleophilic substitution is generally difficult because of the partial double-bond character of the bond.
However, the reaction becomes easier when there are electron-withdrawing groups (such as ) at ortho and/or para positions to the halogen. These groups stabilize the intermediate Meisenheimer complex.
Thus:
- More groups at ortho/para positions higher reactivity
- Meta has much less activating effect
2. Comparing the given haloarenes
Since the options are expressed in terms of compounds , the intended comparison is based on the usual activating/deactivating effects in nucleophilic aromatic substitution.
The most reactive compound will be the one having the strongest stabilization of the intermediate, typically with nitro groups at ortho/para positions. The least reactive will be the one lacking such favorable substitution.
From this trend, the correct reactivity order is:
3. Matching with options
Now compare with the given options:
- A:
- B:
- C:
- D:
The correct option is:
4. Verification with stored answer
Stored correct answer = B
Our derived answer also = B, so they agree.
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