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Haloalkanes and Haloarenes question

2022 · 29 Jun · Shift 2 · Q9
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Haloalkanes and Haloarenes question

2022 · 29 Jun · Shift 2 · Q9

JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
JEE Main 2022 (Online) 29th June Evening Shift Chemistry - Haloalkanes and Haloarenes Question 80 English The stable carbocation formed in the above reaction is
  1. A
    CH3CH2C⊕H2C{H_3}C{H_2}\mathop C\limits^ \oplus {H_2}CH3​CH2​C⊕​H2​
  2. B
    CH3C⊕H2C{H_3}\mathop C\limits^ \oplus {H_2}CH3​C⊕​H2​
  3. C
    CH3−C⊕H−CH3C{H_3} - \mathop C\limits^ \oplus H - C{H_3}CH3​−C⊕​H−CH3​
  4. D
    JEE Main 2022 (Online) 29th June Evening Shift Chemistry - Haloalkanes and Haloarenes Question 80 English Option 4
View written solutionFree

Correct answer: C

  1. Interpret the options

The carbocations shown are:

  • A: CH3CH2CH2+CH_3CH_2CH_2^+CH3​CH2​CH2+​ → primary carbocation
  • B: CH3CH2+CH_3CH_2^+CH3​CH2+​ → primary carbocation
  • C: CH3−C+H−CH3CH_3-\overset{+}{C}H-CH_3CH3​−C+H−CH3​ → secondary carbocation

(Option D is blank.)

  1. Rule for carbocation stability

Carbocation stability generally follows:

3∘>2∘>1∘>CH3+3^\circ > 2^\circ > 1^\circ > CH_3^+3∘>2∘>1∘>CH3+​

This is because alkyl groups stabilize the positively charged carbon by:

  • +I+I+I effect (electron-releasing inductive effect)
  • Hyperconjugation
  1. Compare the given carbocations
  • A: CH3CH2CH2+CH_3CH_2CH_2^+CH3​CH2​CH2+​ is a 1° carbocation
  • B: CH3CH2+CH_3CH_2^+CH3​CH2+​ is also a 1° carbocation
  • C: CH3−C+H−CH3CH_3-\overset{+}{C}H-CH_3CH3​−C+H−CH3​ is a 2° carbocation

A secondary carbocation is more stable than a primary carbocation.

  1. Hence

The most stable carbocation among the given options is:

CH3−C+H−CH3CH_3-\overset{+}{C}H-CH_3CH3​−C+H−CH3​

So, the correct option is C.

  1. Comparison with stored answer

Stored correct answer = C

This matches our derived answer.

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