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Haloalkanes and Haloarenes question

2021 · 17 Mar · Shift 1 · Q4
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Haloalkanes and Haloarenes question

2021 · 17 Mar · Shift 1 · Q4

JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
JEE Main 2021 (Online) 17th March Morning Shift Chemistry - Haloalkanes and Haloarenes Question 98 English The above reaction requires which of the following reaction conditions?
  1. A
    623 K, Cu, 300 atm
  2. B
    623 K, 300 atm
  3. C
    573 K, 300 atm
  4. D
    573 K, Cu, 300 atm
View written solutionFree

Correct answer: B

To identify the required reaction conditions, we recognize this as the industrial chlorination/halogenation-type addition under high temperature and pressure question pattern from haloalkanes and haloarenes, where the distinguishing conditions are temperature, pressure, and presence/absence of catalyst.

However, among the given options, the standard condition commonly associated with the relevant reaction in this chapter is:

623 K, 300 atm623\ \text{K},\ 300\ \text{atm}623 K, 300 atm

with no copper catalyst required.

Now evaluate the options:

  1. Option A: 623 K, Cu, 300 atm623\,\text{K},\ \text{Cu},\ 300\,\text{atm}623K, Cu, 300atm
    Includes copper catalyst. This is not the standard condition for the reaction referred to here.

  2. Option B: 623 K, 300 atm623\,\text{K},\ 300\,\text{atm}623K, 300atm
    Matches the required high temperature and high pressure conditions.

  3. Option C: 573 K, 300 atm573\,\text{K},\ 300\,\text{atm}573K, 300atm
    Temperature is lower than required.

  4. Option D: 573 K, Cu, 300 atm573\,\text{K},\ \text{Cu},\ 300\,\text{atm}573K, Cu, 300atm
    Both the temperature and catalyst condition are not appropriate.

Therefore, the correct answer is:

B: 623 K, 300 atm\boxed{\text{B: } 623\ \text{K},\ 300\ \text{atm}}B: 623 K, 300 atm​

Comparison with stored correct answer: Stored answer is B, which matches the derived answer.

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