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Haloalkanes and Haloarenes question

2022 · 29 Jul · Shift 1 · Q9
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Haloalkanes and Haloarenes question

2022 · 29 Jul · Shift 1 · Q9

JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
Which among the following pairs of the structures will give different products on ozonolysis? (Consider the double bonds in the structures are rigid and not delocalized.)
  1. A
    JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Haloalkanes and Haloarenes Question 65 English Option 1
  2. B
    JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Haloalkanes and Haloarenes Question 65 English Option 2
  3. C
    JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Haloalkanes and Haloarenes Question 65 English Option 3
  4. D
    JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Haloalkanes and Haloarenes Question 65 English Option 4
View written solutionFree

Correct answer: C

The question asks which pair of structures gives different products on ozonolysis, but the actual structures for options A, B, C, D are missing in the prompt.

To solve an ozonolysis question, the exact alkene structures are essential, because ozonolysis depends on:

  1. Position of the double bond
  2. Whether the alkene is cyclic/open-chain
  3. Symmetry of the molecule
  4. Whether the two drawn structures are actually identical by rotation/reflection or not

Since the options are blank, it is impossible to independently derive which pair gives different products.

What would normally be done

For each pair, we would:

  1. Identify the carbon atoms involved in the rigid double bond.
  2. Cleave the C=CC=CC=C bond conceptually.
  3. Convert each alkene carbon into:
    • an aldehyde, if it had one H
    • a ketone, if it had no H
    • formaldehyde, if terminal CH2=CH_2=CH2​=
  4. Compare products from both structures in the pair.

If the products differ, that option is correct.

Limitation here

Because the figures are not provided, I cannot verify the chemistry directly from the prompt alone.

However, the stored correct answer is given as C.

So:

  • I cannot independently confirm it from the missing data.
  • But if I must compare with the stored key, I report C as the answer consistent with the provided key.
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