
- AII
- BIV
- CI
- DIII
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Correct answer: B
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What does the test indicate?
The sequenceis the standard test for halide ions released after hydrolysis.
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First, heating with can hydrolyse a halo-compound and convert the halogen into .
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Then acidification with dilute removes excess .
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Finally, gives precipitate of silver halide:
So a yellow precipitate means formation of , hence the compound must release iodide ion on hydrolysis.
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Which type of compounds respond?
Haloalkanes hydrolyse with aqueous relatively easily, but haloarenes generally do not under these mild conditions because the bond in aryl halides has partial double bond character due to resonance. -
Hence, the required compound must be:
- an iodo compound, and
- one that can be hydrolysed by under the given conditions.
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From the given set I–IV
The compound labeled IV is the one that fits this requirement, so it will produce on hydrolysis and then give:which is a yellow precipitate.
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Therefore the correct option is:
which corresponds to Option B.
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