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Correct answer: 3
- Find molar mass of compound from vapour data
At STP, mole of gas occupies .
Given volume of vapour:
So moles of are:
Given mass of is , hence molar mass:
- Use the fact that is a chloro compound
Let the molecular formula of a monochloro compound be:
Its molar mass is:
So,
Now test integer values of :
- If , then impossible
- If , then impossible
- If , then possible, giving formula:
- If , then impossible
Thus the molecular formula is:
So the compound has 3 carbon atoms.
- Check ozonolysis condition
Degree of unsaturation for :
For a saturated acyclic monochloro compound, formula would be . For , saturated formula is . But actual formula is , i.e. it has two fewer H, so it contains one double bond.
Hence is an alkenyl chloride.
A suitable structure is allyl chloride:
On ozonolysis of the double bond followed by hydrolysis, it forms aldehyde-containing products (notably formaldehyde), which is consistent with the statement.
Thus the data are self-consistent.
- Final answer
The number of carbon atoms in compound is:
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