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Electrochemistry question

2022 · 29 Jun · Shift 2 · Q17
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Electrochemistry question

2022 · 29 Jun · Shift 2 · Q17

JEE MainChemistryElectrochemistryNumerical+4 / −1
The cell potential for the given cell at 298 K Pt| H2H_2H2​ (g, 1 bar) | H+H^+H+ (aq) || Cu2+Cu^{2+}Cu2+ (aq) | Cu(s) is 0.31 V. The pH of the acidic solution is found to be 3, whereas the concentration of Cu2+Cu^{2+}Cu2+ is 10 −-− x M. The value of x is ‾\underline{\hspace{2cm}}​. (Given : ECu2+/CuΘE_{C{u^{2 + }}/Cu}^\ThetaECu2+/CuΘ​= 0.34 V and 2.303 RTF{{2.303\,RT} \over F}F2.303RT​ = 0.06 V)
Numerical answer
View written solutionFree

Correct answer: 7

  1. Write the cell and identify half-cells

The cell is:

Pt∣H2(1 bar)∣H+(aq)∣∣Cu2+(aq)∣Cu(s)\text{Pt} | H_2(1\,\text{bar}) | H^+(aq) || Cu^{2+}(aq) | Cu(s)Pt∣H2​(1bar)∣H+(aq)∣∣Cu2+(aq)∣Cu(s)

Left electrode is the hydrogen electrode and right electrode is the copper electrode.

  1. Find standard cell potential

Given:

ECu2+/Cu∘=0.34 VE^\circ_{Cu^{2+}/Cu} = 0.34\,\text{V}ECu2+/Cu∘​=0.34V

For the standard hydrogen electrode,

EH+/H2∘=0 VE^\circ_{H^+/H_2} = 0\,\text{V}EH+/H2​∘​=0V

So,

Ecell∘=Ecathode∘−Eanode∘=0.34−0=0.34 VE^\circ_{cell} = E^\circ_{cathode} - E^\circ_{anode} = 0.34 - 0 = 0.34\,\text{V}Ecell∘​=Ecathode∘​−Eanode∘​=0.34−0=0.34V

  1. Write the overall cell reaction

Anode (oxidation):

H2→2H++2e−H_2 \rightarrow 2H^+ + 2e^-H2​→2H++2e−

Cathode (reduction):

Cu2++2e−→CuCu^{2+} + 2e^- \rightarrow CuCu2++2e−→Cu

Overall reaction:

H2+Cu2+→2H++CuH_2 + Cu^{2+} \rightarrow 2H^+ + CuH2​+Cu2+→2H++Cu

Thus,

n=2n = 2n=2

  1. Write reaction quotient

For the reaction

H2+Cu2+→2H++CuH_2 + Cu^{2+} \rightarrow 2H^+ + CuH2​+Cu2+→2H++Cu

Q=[H+]2PH2[Cu2+]Q = \frac{[H^+]^2}{P_{H_2}[Cu^{2+}]}Q=PH2​​[Cu2+][H+]2​

Since PH2=1P_{H_2} = 1PH2​​=1 bar,

Q=[H+]2[Cu2+]Q = \frac{[H^+]^2}{[Cu^{2+}]}Q=[Cu2+][H+]2​

  1. Apply Nernst equation

At 298 K298\,K298K,

Ecell=Ecell∘−0.06nlog⁡QE_{cell} = E^\circ_{cell} - \frac{0.06}{n} \log QEcell​=Ecell∘​−n0.06​logQ

0.31=0.34−0.062log⁡([H+]2[Cu2+])0.31 = 0.34 - \frac{0.06}{2} \log \left(\frac{[H^+]^2}{[Cu^{2+}]}\right)0.31=0.34−20.06​log([Cu2+][H+]2​)

0.31=0.34−0.03log⁡([H+]2[Cu2+])0.31 = 0.34 - 0.03 \log \left(\frac{[H^+]^2}{[Cu^{2+}]}\right)0.31=0.34−0.03log([Cu2+][H+]2​)

  1. Use pH = 3

[H+]=10−3[H^+] = 10^{-3}[H+]=10−3

So,

[H+]2=10−6[H^+]^2 = 10^{-6}[H+]2=10−6

Substitute:

0.31=0.34−0.03log⁡(10−6[Cu2+])0.31 = 0.34 - 0.03 \log \left(\frac{10^{-6}}{[Cu^{2+}] }\right)0.31=0.34−0.03log([Cu2+]10−6​)

Rearranging,

0.03=0.03log⁡(10−6[Cu2+])0.03 = 0.03 \log \left(\frac{10^{-6}}{[Cu^{2+}] }\right)0.03=0.03log([Cu2+]10−6​)

log⁡(10−6[Cu2+])=1\log \left(\frac{10^{-6}}{[Cu^{2+}] }\right) = 1log([Cu2+]10−6​)=1

Hence,

10−6[Cu2+]=101\frac{10^{-6}}{[Cu^{2+}]} = 10^1[Cu2+]10−6​=101

[Cu2+]=10−7 M[Cu^{2+}] = 10^{-7}\,M[Cu2+]=10−7M

  1. Compare with given form

Given concentration of Cu2+Cu^{2+}Cu2+ is 10−x M10^{-x}\,M10−xM.

So,

10−x=10−710^{-x} = 10^{-7}10−x=10−7

Therefore,

x=7x = 7x=7

  1. Comparison with stored answer

Stored correct answer = 7, which matches our result.

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