JEE MainChemistryElectrochemistryNumerical+4 / −1
The cell potential for the given cell at 298 K Pt| (g, 1 bar) | (aq) || (aq) | Cu(s) is 0.31 V. The pH of the acidic solution is found to be 3, whereas the concentration of is 10 x M. The value of x is . (Given : = 0.34 V and = 0.06 V)
Numerical answer
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Correct answer: 7
- Write the cell and identify half-cells
The cell is:
Left electrode is the hydrogen electrode and right electrode is the copper electrode.
- Find standard cell potential
Given:
For the standard hydrogen electrode,
So,
- Write the overall cell reaction
Anode (oxidation):
Cathode (reduction):
Overall reaction:
Thus,
- Write reaction quotient
For the reaction
Since bar,
- Apply Nernst equation
At ,
- Use pH = 3
So,
Substitute:
Rearranging,
Hence,
- Compare with given form
Given concentration of is .
So,
Therefore,
- Comparison with stored answer
Stored correct answer = 7, which matches our result.
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