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Electrochemistry question

2022 · 26 Jul · Shift 1 · Q21
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  5. /2022 · 26 Jul · Shift 1 · Q21

Electrochemistry question

2022 · 26 Jul · Shift 1 · Q21

JEE MainChemistryElectrochemistryNumerical+4 / −1
The amount of charge in F\mathrm{F}F(Faraday) required to obtain one mole of iron from Fe3O4\mathrm{Fe}_{3} \mathrm{O}_{4}Fe3​O4​ is ‾\underline{\hspace{2cm}}​. (Nearest Integer)
Numerical answer
View written solutionFree

Correct answer: 3

  1. Find the oxidation states of iron in Fe3O4\mathrm{Fe_3O_4}Fe3​O4​

    We can write: Fe3O4=FeO⋅Fe2O3\mathrm{Fe_3O_4 = FeO \cdot Fe_2O_3}Fe3​O4​=FeO⋅Fe2​O3​

    So in Fe3O4\mathrm{Fe_3O_4}Fe3​O4​:

    • 1 iron is in +2+2+2 state
    • 2 irons are in +3+3+3 state
  2. Electrons needed to reduce iron ions to iron metal

    Reduction to metallic iron:

    • Fe2++2e−→Fe\mathrm{Fe^{2+} + 2e^- \to Fe}Fe2++2e−→Fe
    • Fe3++3e−→Fe\mathrm{Fe^{3+} + 3e^- \to Fe}Fe3++3e−→Fe

    Therefore, for 3 moles of Fe present in Fe3O4\mathrm{Fe_3O_4}Fe3​O4​, total electrons required are: 1×2+2×3=2+6=8 mol e−1\times 2 + 2\times 3 = 2 + 6 = 8\text{ mol e}^-1×2+2×3=2+6=8 mol e−

  3. Charge required per mole of iron

    Since 3 moles of Fe are obtained from 1 mole of Fe3O4\mathrm{Fe_3O_4}Fe3​O4​ using 8 moles of electrons, charge needed for 1 mole of Fe is: 83 F=2.67 F\frac{8}{3}\text{ F} = 2.67\text{ F}38​ F=2.67 F

  4. Nearest integer

    83≈2.67\frac{8}{3} \approx 2.6738​≈2.67 Nearest integer =3= 3=3

Final Answer

3\boxed{3}3​

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