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Electrochemistry question

2019 · 12 Apr · Shift 1 · Q3
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Electrochemistry question

2019 · 12 Apr · Shift 1 · Q3

JEE MainChemistryElectrochemistryMCQ+4 / −1
Given CO3+CO_3^+CO3+​ + e– →\to→ CO2+CO^{2+}CO2+ ; Eo = + 1.81 V Pb4+Pb^{4+}Pb4+ + 2e– →\to→ Pb2+Pb^{2+}Pb2+ ; Eo = + 1.67 V Ce4+Ce^{4+}Ce4+ + e– →\to→ Ce3+Ce^{3+}Ce3+ ; Eo = + 1.61 V Bi3+Bi^{3+}Bi3+ + 3e– →\to→ BiBiBi ; Eo = + 0.20 V Oxidizing power of the species will increase in the order :
  1. A
    Co3+Co^{3+}Co3+ < Ce4+Ce^{4+}Ce4+ < Bi3+Bi^{3+}Bi3+ < Pb4+Pb^{4+}Pb4+
  2. B
    Co3+Co^{3+}Co3+ < Pb4+Pb^{4+}Pb4+ < Ce4+Ce^{4+}Ce4+ < Bi3+Bi^{3+}Bi3+
  3. C
    Ce4+Ce^{4+}Ce4+ < Pb4+Pb^{4+}Pb4+ < Bi3+Bi^{3+}Bi3+ < Co3+Co^{3+}Co3+
  4. D
    Bi3+Bi^{3+}Bi3+ < Ce4+Ce^{4+}Ce4+ < Pb4+Pb^{4+}Pb4+ < Co3+Co^{3+}Co3+
View written solutionFree

Correct answer: D

  1. Principle used

    Oxidizing power of a species depends on its tendency to get reduced.

    The greater the standard reduction potential E∘E^\circE∘, the greater is the tendency to gain electrons, and hence the stronger oxidizing agent.

  2. Given standard reduction potentials

    Co3++e−→Co2+,E∘=+1.81 VCo^{3+} + e^- \to Co^{2+}, \quad E^\circ = +1.81\,\text{V}Co3++e−→Co2+,E∘=+1.81V Pb4++2e−→Pb2+,E∘=+1.67 VPb^{4+} + 2e^- \to Pb^{2+}, \quad E^\circ = +1.67\,\text{V}Pb4++2e−→Pb2+,E∘=+1.67V Ce4++e−→Ce3+,E∘=+1.61 VCe^{4+} + e^- \to Ce^{3+}, \quad E^\circ = +1.61\,\text{V}Ce4++e−→Ce3+,E∘=+1.61V Bi3++3e−→Bi,E∘=+0.20 VBi^{3+} + 3e^- \to Bi, \quad E^\circ = +0.20\,\text{V}Bi3++3e−→Bi,E∘=+0.20V

  3. Arrange by increasing oxidizing power

    Since oxidizing power increases with increasing E∘E^\circE∘:

    0.20<1.61<1.67<1.810.20 < 1.61 < 1.67 < 1.810.20<1.61<1.67<1.81

    Therefore,

    Bi3+<Ce4+<Pb4+<Co3+Bi^{3+} < Ce^{4+} < Pb^{4+} < Co^{3+}Bi3+<Ce4+<Pb4+<Co3+

  4. Match with options

    This corresponds to Option D.

  5. Conclusion

    The increasing order of oxidizing power is:

    Bi3+<Ce4+<Pb4+<Co3+\boxed{Bi^{3+} < Ce^{4+} < Pb^{4+} < Co^{3+}}Bi3+<Ce4+<Pb4+<Co3+​

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